Abstract
The crystal and molecular structure of the title compound, C51H57N3O6S3·CH2Cl2 has been determined by single crystal X-ray analysis and refined to anR-value of 0.069 for 1032 reflections. The crystal is trigonal, space groupR3, witha = 21.255(7),c = 11.317(4), andZ = 3. One molecule of dichloromethane used as solvent is enclathrated in the crystal lattice.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
F. Bottino, M. Di Grazia, P. Finocchiaro, F. R. Fronczek, A. Mamo, and S. Pappalardo,J. Org. Chem. 53, 3521 (1988).
D. D. MacNicol:Structure and Design of Inclusion Compounds: the Hexa-host and Symmetry Considerations (Inclusion Compounds Vol. 2, Eds. J. L. Atwood, J. E. D. Davies, D. D. MacNicol), pp. 123–168. Academic Press (1984).
P. Main, S. J. Fiske, S. E. Hull, L. Lessinger, G. Germain, J.-P. Declercq, and M. M. Woolfson.MULTAN 11/82. A System of Computer Programs for the Automatic Solution of Crystal Structures from X-ray Diffraction Data. University of York, York, England (1982).
B. A. Frenz, SD.Structure Determination Package. College Station, Texas, and Enraf-Nonius, Delft Associates Inc. (1985).
G. M. Sheldrick,SHELX76. Program for Crystal Structure Determination. University of Cambridge, Cambridge, England (1976).
International Tables for X-Ray Crystallography. Vol. IV. Birmingham: Kynoch Press (1974). Distributed by Kluwer Academic Publishers, Dordrecht.
Y. Urushigawa, T. Inazu, and T. Yoshino,Bull. Chem. Soc. Jpn. 44, 2546 (1971).
I. Tabushi, H. Sasaki, and Y. Kuroda,J. Am. Chem. Soc. 98, 5727 (1976).
I. Tabushi, Y. Kuroda, and Y. Kimura,Tetrahedron Lett., 3327 (1976).
S. J. Abbott, A. G. M. Barrett, C. R. A. Godfrey, S. B. Kalindjian, G. W. Simpson, and D. J. Williams,J. Chem. Soc., Chem. Commun., 796 (1982).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Bottino, F., Finocchiaro, P., Lipkowski, J. et al. Crystal and molecular structure ofN,N′,N″-tritosyl-5,8,14,17,23,26-hexamethyl-2,11,20-triaza[3.3.3]-paracyclophane 1 : 1 dichloromethane clathrate. J Incl Phenom Macrocycl Chem 11, 41–48 (1991). https://doi.org/10.1007/BF01073682
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF01073682