Skip to main content
Log in

The formation and properties of mineral-polyacid cements

Part 1 Ortho- and pyro-silicates

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

A study of the cement-forming reactions between certain naturally occurringortho- andpyro-silicate minerals and aqueous polyacid solutions is presented with particular reference to the rheological characteristics of the cement mixtures and the mechanical properties of the hardened cement pastes. The hydrolytic stability of the cements is discussed in terms of the nature of cations present in the gel matrix.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. J. Elliott, L. Holliday andP. R. Hornsby,Brit. Polym. J. 7 (1975) 297.

    Google Scholar 

  2. A. D. Wilson,ibid. 6 (1974) 165.

    Google Scholar 

  3. D. C. Smith,Brit. Dent. J. 125 (1968) 381.

    Google Scholar 

  4. A. Jurecic, Canadian Patent no. 909 414, September (1972).

  5. A. D. Wilson andB. E. Kent, British Patent no. 1 316 129, May (1973).

  6. S. Crisp andA. D. Wilson, in “Ionic Polymers”, edited by L. Holliday, (Applied Science Publishers, London, 1975) Ch. 4.

    Google Scholar 

  7. B. E. Kent andA. D. Wilson,Brit. Dent. J. 135 (1973) 322.

    Google Scholar 

  8. A. D. Wilson, in “Scientific Aspects of Dental Materials”, edited by J. A. Fraunhofer (Butterworths, London, 1975) p. 211ff.

    Google Scholar 

  9. J. W. Mclean, andA. D. Wilson,Austral. Dent. J. 22 (1977) 31.

    Google Scholar 

  10. S. Crisp, A. D. Wilson, J. H. Elliott andP. R. Hornsby,J. Appl. Chem. Biotechnol. 27 (1977) 369.

    Google Scholar 

  11. British Standards Specifications for Dental Silicate Cement and Dental Silicophosphate Cement, Part 2, BS 3365 (1971).

  12. C. G. Plant, I. H. Jones, andH. J. Wilson,Brit. Dent. J. 133 (1972) 21.

    Google Scholar 

  13. C. R. Orcel,Acad. Sci. Paris 236 (1953) 1052.

    Google Scholar 

  14. R. C. Mackenzie “Scifax-Differential Thermal Analysis Data Index” (Cleaver-Hume Press, London, 1962).

    Google Scholar 

  15. A. J. Kauffman andE. D. Dilling,Econ. Geol. 45 (1950) 222.

    Google Scholar 

  16. R. C. Mackenzie, (Ed.) “Differential Thermal Investigation of Clays” (London Mineralogical Society, 1957).

  17. G. T. Faust,Amer. Mineral. 36 (1951) 795.

    Google Scholar 

  18. S. Cross,Israel. J. Chem. 9 (1971) 601.

    Google Scholar 

  19. P. R. Hornsby, PhD Thesis, Brunel University, (1977).

  20. A. D. Wilson, S. Crisp andA. J. Ferner,J. Dent. Res. 55 (1976) 489.

    Google Scholar 

  21. E. S. Dana, “A Textbook of Mineralogy”, revised by W. E. Ford, 4th edn. (Wiley, New York and London, 1966).

    Google Scholar 

  22. H. Mase,J. Chem. Soc. Japan 34 (1961) 214.

    Google Scholar 

  23. J. A. Gadsen, “I.R. Spectra of Minerals and Related Inorganic Compounds” (Butterworths, London, 1975).

    Google Scholar 

  24. K. Nakamoto, “Infra-red spectra of Inorganic and Co-ordination Compounds”, 2nd edn. (Wiley-Interscience, New York and London, 1970).

    Google Scholar 

  25. J. Zussman, (Ed.), “Physical Methods in Determinative Mineralogy” (Academic Press, New York and London, 1967).

    Google Scholar 

  26. S. Crisp, H. J. Prosser andA. D. Wilson,J. Mater. Sci. 11 (1976) 36.

    Google Scholar 

  27. A. Ikegami,J. Polymer Sci. A2 (1964) 907.

    Google Scholar 

  28. Idem, Biopolymers 6 (1968) 431.

    Google Scholar 

  29. S. Crisp, A. J. Ferner, B. G. Lewis andA. D. Wilson,J. Dentistry 3 (1975) 125.

    Google Scholar 

  30. A. L. Reader andK. A. Hodd,Brit. Polymer. J. 8 (1976) 131.

    Google Scholar 

  31. H. P. Gregor, L. B. Luttinger andE. M. Loebl,J. Phys. Chem. 59 (1955) 990.

    Google Scholar 

  32. A. D. Wilson andS. Crisp,Brit. Polym. J. 7 (1975) 279.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Crisp, S., Merson, S., Wilson, A.D. et al. The formation and properties of mineral-polyacid cements. J Mater Sci 14, 2941–2958 (1979). https://doi.org/10.1007/BF00611479

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00611479

Keywords

Navigation