Skip to main content
SpringerLink
Log in

Application of kinetic methods in studying the defect concentrations and their mobility in transition metal oxides

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

A critical discussion of two new methods for investigating the concentration and mobility of point defects in the crystalline lattice of metal oxides is presented. These methods are based on kinetic measurements of metal oxidation in specialized conditions. Using the results obtained on the cobalt-cobaltous oxide-oxygen model system, it has been shown that both these methods lead to correct results being simultaneously more simple and accurate than the classical ones.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. K. Hauffe, “Reaktionen in und an festen Stoffen” (Springer, Berlin, 1966).

    Google Scholar 

  2. P. Kofstad, “Nonstoichiometry, Diffusion, and Electrical Conductivity in Binary Metal Oxides” (Wiley — Interscience, New York, 1972).

    Google Scholar 

  3. W. Van Gool, “Fast Ion Transport in Solids” (Elsevier, Amsterdam, 1973).

    Google Scholar 

  4. F. Kröger, “The Chemistry of Imperfect Crystals” (North-Holland, Amsterdam, 1964).

    Google Scholar 

  5. P. Shewmon, “Diffusion in Solids” (McGraw-Hill, New York, 1963).

    Google Scholar 

  6. S. Mrowec, “Defekty struktury i dyfuzja atomów w kryształach jonowych” (PWN, Warszawa, 1974).

    Google Scholar 

  7. E. Fryt, S. Mrowec and T. Walec, Zeszyty Naukowe AGH, Zeszyt Specjalny 30 (1972) 131.

    Google Scholar 

  8. I. Bartkowicz, E. Fryt and S. Mrowec, Bull. Acad. Polon. Sci., Ser. Sci. Chim. 16 (1968) 263.

    Google Scholar 

  9. E. Fryt, S. Mrowec and T. Walec, Oxidation of Metals 7 (1973) 117.

    Google Scholar 

  10. Idem, “Oxidation Kinetic Method for studying the Defect Concentration and their Mobility in Metal Oxides”, Proceedings of the International Symposium on Materials Science, Kraków 26–29 November 1973 p. 162.

  11. E. Fryt and S. Mrowec, J. Mater. Sci., in press.

  12. S. Mrowec and A. Stokłosa, Oxidation of Metals 3 (1971) 291.

    Google Scholar 

  13. S. Mrowec, T. Walec and T. Werber, Corrosion Sci. 6 (1966) 287.

    Google Scholar 

  14. G. Tammann, Z. anorg. allg. Chem. 123 (1920) 196.

    Google Scholar 

  15. P. Kofstad, “High-Temperature Oxidation of Metals” (Wiley, New York, 1966) p. 112.

    Google Scholar 

  16. K. Hauffe, Oxydation von Metallen und englerungen (Springer, Berlin, 1957).

    Google Scholar 

  17. O. Kubaschewski and B. Hopkins, “Oxidation of Metals and Alloys” (Butterworth, London, 1962).

    Google Scholar 

  18. S. Mrowec, “Zarys teorii utleniania metali” Wyd. “Šlask” (Katowice, 1971) p. 150.

  19. C. Wagner, “Diffusion and High Temperature Oxidation of Metals” in “Atom Movements” (ASM, Cleveland, 1951) p. 153.

    Google Scholar 

  20. K. Fueki and J. Wagner, J. Electrochem. Soc. 112 (1965) 384.

    Google Scholar 

  21. H. Engell, Acta Met. 6 (1958) 439.

    Google Scholar 

  22. F. Pettit, J. Electrochem. Soc. 113 (1966) 1250.

    Google Scholar 

  23. S. Mrowec, Bull. Acad. Polon. Sci., Ser. Sci. Chim. 15 (1967) 373.

    Google Scholar 

  24. Idem, ibid 15 (1967) 15.

    Google Scholar 

  25. S. Mrowec and A. Stokłosa, ibid, 18 (1970) 523.

    Google Scholar 

  26. A. Brückman, Corrosion Sci. 7 (1967) 51.

    Google Scholar 

  27. S. Mrowec, ibid 7 (1967) 563.

    Google Scholar 

  28. J. Romański, ibid 8 (1968) 67; 8 (1968) 89.

    Google Scholar 

  29. S. Mrowec and A. Stokłosa, Werkstoffe und Korrosion 21 (1970) 934.

    Google Scholar 

  30. Idem, Oxidation of Metals, in press.

  31. N. Pilling and R. Bedworth, J. Inst. Metals 29 (1923) 529.

    Google Scholar 

  32. C. Wagner, Z. Physik. Chem. 21 (1933) 25; 32 (1936) 447.

    Google Scholar 

  33. S. Mrowec, T. Walec and T. Werber, Bull. Acad. Polon. Ser. Sci. Chim. 14 (1966) 179.

    Google Scholar 

  34. S. Mrowec and K. Przybylski, Oxidation of Metals, in press.

  35. Idem, Bull. Acad. Polon. Sci., Ser. Sci. Chim., in press.

  36. R. Carter and F. Richardson, J. Metals 6 (1954) 1244.

    Google Scholar 

  37. B. Fisher and D. Tannhauser, J. Electrochem. Soc. 111 (1964) 1195.

    Google Scholar 

  38. N. Eror and J. Wagner, J. Phys. Chem. Solids 29 (1968) 1597.

    Google Scholar 

  39. H. Sockel and H. Schmalzried, Ber. Bunsen, Gessell-Schaft Phys. Chemie 72 (1968) 745.

    Google Scholar 

  40. W. Chen, N. Peterson and W. Reeves, Phys. Rev. 186 (1969) 897.

    Google Scholar 

  41. J. Price and J. Wagner, Z. Phys. Chem. N.F. 49 (1966) 257.

    Google Scholar 

  42. B. Fisher and D. Tannhauser, J. Chem. Phys. 44 (1966) 1663.

    Google Scholar 

  43. G. Koel and P. Gellings, Oxidation of Metals 5 (1972) 185.

    Google Scholar 

  44. R. Carter and F. Richardson, J. Metals 7 (1955) 336.

    Google Scholar 

  45. D. Bridges, J. Baur and W. Fassel, J. Electrochem. Soc. 103 (1956) 619.

    Google Scholar 

  46. J. Kröger, A. Melin and H. Winterhager, Cobalt 33 (1964) 41.

    Google Scholar 

  47. J. Snide, J. Myers and R. Saxer, ibid 36 (1967) 157.

    Google Scholar 

  48. J. Manning, “Diffusion Kinetics for Atoms in Crystals” (Van Nostrand, New Jersey, 1968) p. 95.

    Google Scholar 

  49. W. Moore and B. Selikson, J. Chem. Phys. 19 (1951) 1539.

    Google Scholar 

  50. N. Mott and R. Gurney, “Electronic Processes in Ionic Crystals” (Clarendon Press, Oxford, 1948) p. 257.

    Google Scholar 

  51. A. Rosenberg, J. Electrochem. Soc. 107 (1960) 795.

    Google Scholar 

  52. T. Smyth, ibid 112 (1965).

  53. I. Bartkowicz, E. Fryt and S. Mrowec, Roczniki Chemii, in press.

  54. E. Fryt and S. Mrowec, unpublished work.

Download references

Author information

Authors and Affiliations

  1. Academy of Mining and Metallurgy, Institute of Materials Science, Kraków, Poland

    Stanisław Mrowec

Authors
  1. Stanisław Mrowec
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mrowec, S. Application of kinetic methods in studying the defect concentrations and their mobility in transition metal oxides. J Mater Sci 9, 1961–1976 (1974). https://doi.org/10.1007/BF00540545

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00540545

Keywords

Search

Navigation