Skip to main content
Log in

Determinations of boron and chloride in highly radioactive sample solution

  • Radioanalytical Methods and Technology: Specialized Methods
  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

To meet the requirements of NUREG-0737 and Atomic Energy Council, Republic of China, the post accident sampling systems have recently been established at Taiwan power stations. The lead shielded cask for transportation of grab liquid sample from sampling station to the off-site backup laboratory was designed, based on the functions of sample taken vertically from sample station and the horizontal transferring of sample vial to the cell of backup laboratory. Spectrophotometric, titrimetric and ion chromatographic methods were studied and comparisons made for the analyses of boron and chloride. It can be concluded that suppressed ion chromatography with remote handling in a lead cell is best for determining boron and chloride simultaneously in a high radioactive sample solution. The method with high accuracy, less interference and rapid analysis is considered and discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. USNRC, Clarification of TMI Action Plan Requirement, NUREG-0703 Item II, B, 3, 1982.

  2. USNRC Regulatory Guide 1.97, Instrumentation for Light-Water Cooled Nuclear Power Plants to Asses Plant and Environs Conditions During and Following an Accident, Revision 3, 1983.

  3. R. E. KIRK, O. F. OTHMER, Encyclopedia of Chemical Technology, 3rd Edition, Wiley-interscience, New York, Vol. 4, 1966, p. 62.

    Google Scholar 

  4. J. AZNAREZ, J. M. MIR, Analyst, 110 (1985) 61.

    Article  Google Scholar 

  5. D. MIDGLEY, Analyst, 110 (1985) 841.

    Article  Google Scholar 

  6. M. DOI, K. ABE, T. HATTORI, Prediction Methods Assessment of Corrosion Damage in BWR Piping and PWR Steam Generators (Conf.) 306 (1982).

  7. H. SAMLL, T. S. STEVENS and W. C. BAUMAN, Anal. Chem., 47 (1975) 1081.

    Article  Google Scholar 

  8. C. A. POHL, E. L. JOHNSON, J. Chromatogr., 18 (1980) 422.

    Google Scholar 

  9. M. N. ROBLES et al., Water Chemistry, Nucl. React. Syst., (BENS, London) 3 (1983) 339.

    Google Scholar 

  10. ASTM D4327-84.

  11. Communications with Health Physic Division and Nuclear Engineering Division, Institute of Nuclear Energy Research, 1986.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chen, CC., Lee, CS. & Cheng, WL. Determinations of boron and chloride in highly radioactive sample solution. Journal of Radioanalytical and Nuclear Chemistry, Articles 123, 421–442 (1988). https://doi.org/10.1007/BF02034908

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02034908

Keywords

Navigation