Abstract
Chlorobis/β-diketonato/ oxotechnetium/V/ complexes [TcOCl/β-dik/2, β-diketone=acetylacetone, benzoylacetone and dibenzoylmethane] were newly synthesized using macroamount of99Tc. These complexes were further separated into geometrical isomers. Furthermore, an improvement of the yields for the syntheses of tris/β-dike-tonato/technetium/III/ complexes [Tc/β-dik/3, β-diketone=acetylacetone, benzoylacetone and 2-thenoyltrifluoroacetone] was examined using Tc/III/-thiourea complexes as a starting material.
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Hashimoto, K., Yamada, Y., Omori, T. et al. Synthesis of chlorobis/β-diketonato/oxotechnetium/V/ and tris/β-diketonato/technetium/III/ complexes. Journal of Radioanalytical and Nuclear Chemistry Letters 135, 187–197 (1989). https://doi.org/10.1007/BF02164971
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DOI: https://doi.org/10.1007/BF02164971