Skip to main content
SpringerLink
Log in

A New Theoretical Approach to Steady State of Temperature Modulated Heat Flux DSC

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

The steady state of temperature modulated heat flux DSC, in which the sample temperature is controlled at a fixed frequency, a fixed amplitude and a constant underlying heating rate, is theoretically investigated for complex heat capacity of the sample, taking accounts of heat capacities of heat paths, heat loss to the environment and mutual heat exchange between the sample and the reference material. Rigorous and general solutions for the temperature difference oscillation are obtained in relation to the sample temperature as a reference oscillation. The results are quite different from those obtained in functions of the heat source temperature as a reference oscillation. From these solutions, application of the technique to heat capacity measurements is discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. Reading, D. Elliott and V. L. Hill, J. Thermal Anal., 40 (1993) 949.

    CAS  Google Scholar 

  2. P. S. Gill, S. R. Sauerbrunn and M. Reading J. Thermal Anal., 40 (1993) 931.

    CAS  Google Scholar 

  3. J. Schawe, Thermochim. Acta, 260 (1995) 1.

    Article  CAS  Google Scholar 

  4. R. Riesen, G. Widmann and R. Truttmann, Thermochim. Acta, 268 (1995) 1.

    Article  Google Scholar 

  5. M. Nishikawa and Y. Saruyama, Thermochim. Acta, 267 (1995) 75.

    Article  CAS  Google Scholar 

  6. T. Ozawa and K. Kanari, Thermochim. Acta, 288 (1996) 39.

    Article  CAS  Google Scholar 

  7. B. Wunderlich, Y. Jin and A. Boller, Thermochim. Acta, 238 (1994) 277.

    Article  CAS  Google Scholar 

  8. A. Boller, Y. Jin and B. Wunderlich, J. Thermal Anal., 42 (1994) 307.

    CAS  Google Scholar 

  9. I. Hatta and S. Muramatsu, Jpn. J. Appl. Phys., 35 (1996) L858.

    Article  CAS  Google Scholar 

  10. J. E. K. Schawe and W. Winter, Thermochim. Acta, 298 (1997) 9.

    Article  CAS  Google Scholar 

  11. A. A. Lacy, C. Nickopoulos and M. Reading, J. Thermal Anal., 50 (1997) 279.

    Article  Google Scholar 

  12. T. Ozawa and K. Kanari, Thermochim. Acta, 253 (1995) 183.

    Article  CAS  Google Scholar 

  13. T. Ozawa, Bull. Chem. Soc. Jpn., 39 (1966) 2071.

    CAS  Google Scholar 

  14. T. Ozawa, Netsu Sokutei, 4 (1977) 45.

    CAS  Google Scholar 

  15. M. J. O'Neill, Anal. Chem., 36 (1964) 1238.

    Article  Google Scholar 

  16. K. Kanari and T. Ozawa, Thermochim. Acta, 304/305 (1997) 201.

    Article  CAS  Google Scholar 

  17. N. O. Birge, P. K. Dixon and N. Menon, Thermochim. Acta, 304/305, (1997) 51.

    Article  CAS  Google Scholar 

  18. Y. Saruyama, Thermochim. Acta, 282/283 (1996) 157.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Chiba Institute of Technology, Tsudanuma, 275-8588

    T. Ozawa

  2. Electrotechnical Laboratory, Tsukuba, 305-8568, Japan

    K. Kanari

Authors
  1. T. Ozawa
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. K. Kanari
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ozawa, T., Kanari, K. A New Theoretical Approach to Steady State of Temperature Modulated Heat Flux DSC. Journal of Thermal Analysis and Calorimetry 54, 521–534 (1998). https://doi.org/10.1023/A:1010186324376

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1010186324376

Search

Navigation