Abstract
The kinetics of methanation of CO and CO2 were markedly different in the transient state. The hydrogenation of surface carbon species was strongly inhibited by reversibly adsorbed CO in the former reaction. CO2 did not inhibit the latter reaction and H2O was found to form by two distinct steps.
Abstract
Кинетики метанирования CO и CO2 значительно различаются в промежуточном состоянии. Гидрирование поверхностных углеродных частиц сильно ингибировано CO, обратимо адсорбированным в реакции метанирования, а CO2 не ингибирует последнюю реакцию и H2O образуется на двух различных ступенях.
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Fujita, S., Terunuma, H., Kobayashi, H. et al. Methanation of carbon monoxide and carbon dioxide over nickel catalyst under the transient state. React Kinet Catal Lett 33, 179–184 (1987). https://doi.org/10.1007/BF02066720
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DOI: https://doi.org/10.1007/BF02066720