Summary
The complex [PhCH2PPh3]2[Mo2O2S2(SC2H4S)2] has been prepared by reaction of [PhCH2PPh3][MoO(SC2H4S)2] with phenylhydrazine and characterized by single-crystal x-ray structure analysis. This revealed that each molybdenum displays square pyramidal geometry with the terminal oxo-groups in the apical position and the sulphur donors of the dimer-captoethane ligand and the bridging sulphido-ligands generating the basal plane. The related complex [HNEt3]2-[Mo2S4(SC2H4S)2], synthesised by reaction of the MoVI butandiolato-complex [MoO2(butanediolato)2]: 2(butanediol) with triethylamine and ethanedithiol, has also been characterised crystallographically. The structure displays the previously characterized [Mo2S4]2+ core. The anion geometry is analogous to that observed for the oxo-derivative [Mo2O2S2(SC3H4S)2]−2 with the apical oxo-ligand replaced by a sulphido-group.
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References
See,e.g., C. A. McAuliffe, (Ed.) in F. L. Bowden,Techniques and Topics in Bioinorganic Chemistry, Macmillan, London, 205 (1975).
B. Spivack, A. P. Gaughan and Z. Dori,J. Am. Chem. Soc., 93, 9241 (1971).
R. J. Butcher, H. K. J. Powell, J. Wilkins and S. M. Yong,J. Chem. Soc., Dalton Trans., 356 (1976).
M. W. Bishop, G. Butler, J. R. Dilworth and G. J. Leigh,J. Chem. Soc., Dalton Trans., 1843 (1979).
D. T. Cromer and J. B. Mann,Acta Crystallogr. Sect. A, 24, 321 (1968).
R. F. Stewart, E. R. Davidson and W. T. Simpson,J. Chem. Phys., 42, 375 (1965).
Intl. Tables for X-ray Crystallography, Vol. IV, Tables 2, 3,1. The Kynoch Press, 1974, p. 149.
J. I. Gelder, J. H. Enemark,Inorg. Chem., 15, 1839 (1979).
M. G. B. Drew and A. Kay.J. Chem. Soc. A, 1851 (1971).
D. H. Brown and J. A. D. Jefferys,J. Chem. Soc., Dalton Trans., 732 (1973).
B. Spirack and Z. Dori,J. Chem. Soc., Dalton Trans., 1173 (1973).
P. C. H. Mitchell, Ed. in L. F. Dahl, P. D. Frisch and G. R. Gest,Proceedings of the Climax First International Symposium on Chemistry and Use of Molybdenum, Climax Molybdenum Co. London 1973, p. 134.
B. Spivack, Z. Dori and E. I. Stiefel,Inorg. Nucl. Chem. Lett., 11, 501 (1975).
G. Bunzey and J. H. Enemark,Inorg. Chem., 17, 682 (1978).
J. K. Howie and D. T. Sawyer,Inorg. Chem., 15, 1892 (1976).
F. A. Schultz, V. R. Ott, D. S. Rolison, D. C. Bravard, J. W. McDonald, W. E. Newton,Inorg. Chem., 17, 1758 (1978).
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Hsieh, TC., Gebreyes, K. & Zubieta, J. Studies of molybdenum thiolato-complexes. The chemical characterization and the crystal and molecular structures of two sulphido-bridged Movdimers, [PhCH2PPh3]2[Mo2O2S2(SC2H4S)2] and [HNEt3]2[Mo2S4(SC2H4S)2]. Transition Met Chem 10, 81–84 (1985). https://doi.org/10.1007/BF00618453
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DOI: https://doi.org/10.1007/BF00618453