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The preparation of cobalt complexes containing simple sulphur-nitrogen ligands, S2N2H− and S3N−, from S4N4O2

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Summary

Reactions of Group VIII metal halides [CoCl2, NiCl2, K2PdCl4, PdCl2(PhCN)2 and PtCl2] with tetrasulphurtetranitrogendioxide, S4N4O2, have been investigated. The cobalt reaction yields Co(S2N2H)2, Co(S2N2H)(S3N) and Co(S3N)2. The usefulness of metal centres for trapping reactive sulphur-nitrogen centres is discussed.

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Authors and Affiliations

  1. Department of Chemistry, Imperial College of Science and Technology, SW7 2AY, London, UK

    John C. Burgess, Z. Erhan Tatar & J. Derek Woollins

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  1. John C. Burgess
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  2. Z. Erhan Tatar
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  3. J. Derek Woollins
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Burgess, J.C., Tatar, Z.E. & Woollins, J.D. The preparation of cobalt complexes containing simple sulphur-nitrogen ligands, S2N2H− and S3N−, from S4N4O2 . Transition Met Chem 12, 8–9 (1987). https://doi.org/10.1007/BF01023118

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  • DOI: https://doi.org/10.1007/BF01023118

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