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The preparation of M(PR3)2 (S2(S)PC6H4OMe) (M=Ni, Pd, Pt) from Lawessons reagent

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Summary

Reaction of Lawessons reagent (MeOC6H4P(S)S2P(S)C6H4OMe) (1) withbis-phosphine-dihalide complexes of nickel, palladium and platinum proceeds with asymmetric bridge cleavage to give M(PR3)2(S2(S)PC6H4OMe) (2). The new compounds were characterised by31P n.m.r., i.r. and microanalyses.

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Authors and Affiliations

  1. Department of Chemistry, Imperial College of Science and Technology, South Kensington, SW 7 2AY, London, UK

    Paul T. Wood & J. Derek Woollins

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  1. Paul T. Wood
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  2. J. Derek Woollins
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Wood, P.T., Woollins, J.D. The preparation of M(PR3)2 (S2(S)PC6H4OMe) (M=Ni, Pd, Pt) from Lawessons reagent. Transition Met Chem 12, 403–405 (1987). https://doi.org/10.1007/BF01171647

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  • DOI: https://doi.org/10.1007/BF01171647

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