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Synthesis of s-fac/mer bis(N2-methyldiethylenetriamine, L) nickel(II): X-ray single crystal structures of s-fac[NiL2](NO3)2 and mer[NiL2](CF3CO2)2

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Abstract

[NiL2](NO3)2 (1) and [NiL2](CF3CO2)2 (2) (L = N2-methyldiethylenetriamine] have been synthesized and their X-ray single crystal structures have been determined. The triamines are ligated to NiII s-facially in (1) and meridionally in (2), with a NiN6 chromophore in each complex.

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Authors and Affiliations

  1. Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Calcutta, 700032, India

    Arunendu Mondal, Inamur R. Laskar & Nirmalendu Ray Chaudhuri

  2. X-ray Crystallography Laboratory, Department of Solid State Physics, Indian Association for the Cultivation of Science, Jadavpur, Calcutta, 700032, India

    Golam Mostafa

  3. Department of Chemistry, University College of Science and, Technology, Calcutta, 700009, India

    Ashutosh Ghosh & J. Shashidhara Prasad

Authors
  1. Arunendu Mondal
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  2. Inamur R. Laskar
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  3. Nirmalendu Ray Chaudhuri
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  4. Golam Mostafa
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  5. Ashutosh Ghosh
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  6. J. Shashidhara Prasad
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Mondal, A., Laskar, I.R., Chaudhuri, N.R. et al. Synthesis of s-fac/mer bis(N2-methyldiethylenetriamine, L) nickel(II): X-ray single crystal structures of s-fac[NiL2](NO3)2 and mer[NiL2](CF3CO2)2. Transition Metal Chemistry 24, 282–286 (1999). https://doi.org/10.1023/A:1006999132388

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