Summary
Mössbauer parameters for hexacoordinate iron(II) complexes of the type [Fe(N-N)n(CNMe)m](ClO4)2 (m = 6, 4, 2 or 0; n = 0, 1, 2 or 3; N−N = 2,′ -bipyridine or 1,10-phenanthroline) have been determined. Treatment by a point-charge model including distortions has been carried out in order to rationalize the quadrupole splittings. A computer program has been developed to handle variable geometry systems.
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Calogero, S., Russo, U., Condorelli, L.L. et al. A Mössbauer study of some iron(II) complexes with methyl isocyanide, bipyridine and phenanthroline. Transition Met Chem 4, 156–160 (1979). https://doi.org/10.1007/BF00619058
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DOI: https://doi.org/10.1007/BF00619058