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Transition metal chemistry of oxime-containing ligands, part XXIII; some trinuclear copper(II) complexes of quinoline-2-aldoxime and isoquinoline-3-aldoxime

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Summary

Some copper(II) complexes of types [Cu3(L)3(OH)2](X) and [Cu3(L)3(OH)(SO4)] · 3 H2O (where L=qox, anion of quinoline-2-aldoxime (Hqox) or iqox, anion of isoquinoline-3-aldoxime (Hiqox) and X=Cl, Br, I, NO3, NCS or NCSe) were prepared and characterized by elemental analysis, molecular conductance, magnetic moment (300-77K) and spectral measurements. The complexes are highly antiferromagnetic and have S=1/2. A distorted square-pyramidal structure with CuN2O3 chromophore is proposed.

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Authors and Affiliations

  1. Department of Chemistry, N.R.E.C. College, 203131, Khurja, India

    Madan Mohan & Munesh Kumar

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  1. Madan Mohan
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  2. Munesh Kumar
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Mohan, M., Kumar, M. Transition metal chemistry of oxime-containing ligands, part XXIII; some trinuclear copper(II) complexes of quinoline-2-aldoxime and isoquinoline-3-aldoxime. Transition Met Chem 7, 301–303 (1982). https://doi.org/10.1007/BF00618335

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  • DOI: https://doi.org/10.1007/BF00618335

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