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Crystal structure and spectroscopy of the low-spin iron(II) compound: tris(bipyrimidine)iron(II) bis(triflate), [Fe(bipym)33](CF3SO3)2

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Abstract

The compound [Fe(bipym)33](CF3SO3)2 (in which bipym = 2,2′-bipyrimidine) crystallizes in the space group P21/c, with a = 13.7641(11), b = 18.7557(19), c = 12.3627(11) Å, β = 103.085(8)° and Z = 4. The low-spin Fe(II) atom is octahedrally surrounded by six nitrogen atoms of three bipyrimidine groups with Fe—N distances that vary from 1.968(4) to 1.975(4) å. In the far-infrared region the Fe—N vibrations are observed at 359 and 372 cm-1.

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Authors
  1. Gerard A. van Albada
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  2. Wilberth J.J. Smeets
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  3. Anthony L. Spek
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  4. Jan Reedijk
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van Albada, G.A., Smeets, W.J., Spek, A.L. et al. Crystal structure and spectroscopy of the low-spin iron(II) compound: tris(bipyrimidine)iron(II) bis(triflate), [Fe(bipym)33](CF3SO3)2. Journal of Chemical Crystallography 30, 441–444 (2000). https://doi.org/10.1023/A:1011339214337

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  • DOI: https://doi.org/10.1023/A:1011339214337

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