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Cobalt (iron) thiolato complexes containing the Co-ligand phosphine and reaction products of the structural fragment ML 2 L′ (L = 1,2-bidentate thiolate,L′= tertiary phosphine)

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Abstract

Mono-, di-, tri-, and tetra-nuclear cobalt (iron) complexes containing co-ligands phosphine and thiolate are presented according to the classification by combination of different dentates of the two ligands. Emphasis is being put on the triand tetranuclear cluster complexes of monodentate phosphines and 1,2-bidentate thiolates. These complexes are considered to be constructed based on the general structural fragment (or building block) ML 2L′ (L=1,2-bidentate thiolate,L′=tertiary phosphine). Structural regularities are presented in Tables I, III, IV, and V and discussed. FAB mass spectroscopic data showed the possible fragmentation patterns. Synergism of the cluster skeletons is proposed to explain the occurrence of the distinct structural modes.

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Abbreviations

Bu 3 n P:

tri-n-butylphosphine

dmpe:

1,2-bis(dimethylphosphino)ethane

dmpm:

1,2-bis(dimethylphosphino)methane

dppe:

1,2-bis(diphenylphosphino)ethane

dppep:

bis(2-diphenylphosphinoethyl)phenylphosphine

dppm:

1,1-bis(diphenylphosphino)methane

dppp:

1,3-bis(diphenylphosphino)propane

Et3P:

triethylphosphine

Ph3P:

triphenylphosphine

tepme:

1,1,1-tris(diethylphosphinomethyl)ethane

tppme:

1,1,1-tris(diphenylphosphinomethyl)ethane

H2bdt:

1,2-benzenedithiol

H2edt:

1,2-ethanedithiol

Hmbt:

2-mercaptobenzothiazole

H2mp:

2-mercaptophenol

Hmp:

2-hydroxythiophenolate

Hmpo:

2-mercaptopyridine-N-oxide

H2mpp:

2-mercapto-3-hydroxypyridine

Hmpp:

3-hydroxy-2-pyridinothiolate

H2pdt:

1,2-propanedithiol

HSPh:

thiophenol

H2tdt:

4-methyl-1,2-benzenedithiol(4-toluenedithiol)

R2dtc:

dialkyldithiocarbamate

(RO)2dtp:

dialkyldithiophosphate

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Authors and Affiliations

  1. Department of Chemistry, Zhongshan University, 510275, Guangzhou, Guangdong, China

    Bei-Sheng Kang, Zhong-Ning Chen, Han-Qin Liu & Zhi-Tao Xu

  2. Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 350002, Fuzhou, Fujian, China

    Yuan-Ba Cai & Yong-Jin Xu

  3. Department of Chemistry, Chinese University of Hong Kong, Shatin, New Territories, Hong Kong

    Zhong-Yuan Zhou, Han-Rong Gao, Bo-Mu Wu & Thomas C. W. Mak

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Kang, BS., Chen, ZN., Zhou, ZY. et al. Cobalt (iron) thiolato complexes containing the Co-ligand phosphine and reaction products of the structural fragment ML 2 L′ (L = 1,2-bidentate thiolate,L′= tertiary phosphine). J Clust Sci 7, 317–340 (1996). https://doi.org/10.1007/BF01171186

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