Abstract
Cation- and anion-substituted zirconium phosphates of X kZr m (PO4) n−y Y composition, where X = Na+, La3+, NH4 +, Y = F−, WO4 2−, 1/3 < k < 2, 2 < m < 4, 3 < n < 6 were synthesized by the procedure, including mechanical activation of the starting salts mixture followed by annealing at 300–900°C. The interaction between components was studied by XRD, EXAFS, FT–IR, [31P-MAS] NMR. The possibility of synthesizing nonstoichiometric compounds is demonstrated and prospects for application of the mechanochemical method for synthesis of complex zirconium phosphates are outlined.
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Chaikina, M.V., Sadykov, V.A., Pavlova, S.N. et al. Mechanochemical Synthesis of Complex Zirconium Phosphates. Journal of Materials Synthesis and Processing 8, 279–286 (2000). https://doi.org/10.1023/A:1011334125802
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DOI: https://doi.org/10.1023/A:1011334125802