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Overlooked opportunities in stereochemistry. Part III: Alfred Werner's awareness of spontaneous resolutions and of the meaning of hemihedral faces in optically active crystals

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References

  1. Bernal, I.; Kauffman, G. B.J. Chem. Educ. 1987,64, 604.

    Google Scholar 

  2. Kauffman, G. B.; Bernal, I.J. Chem. Educ. 1989,66, 293.

    Google Scholar 

  3. Pasteur, L.Compt. Rend. 1848,26, 535;Ann. Chim. Phys. 1850,28, 56.

    Google Scholar 

  4. Kauffman, G. B.; Myers, R. D.J. Chem. Educ. 1975,52, 777.

    Google Scholar 

  5. Werner, A.Ber. 1914,47, 2171.

    Google Scholar 

  6. Bosshart, J.Anomale Erscheinungen bei der Spaltung von Racemverbindungen; Inaugural Dissertation; Conzett: Zürich, 1914.

    Google Scholar 

  7. Werner, A.Ber. 1911,44, 1887. For a discussion and annotated English translation see Kauffman, G. B.;Classics in Coordination Chemistry, Part 1: The Selected Papers of Alfred Werner; Dover: New York, 1968; pp 153–173.

    Google Scholar 

  8. Kauffman, G. B.; Lindley, Jr., E. V.J. Chem. Educ. 1974,51, 424;Inorg. Synth. 1976,16, 93.

    Google Scholar 

  9. Duschinsky, R.Chem. Ind. (London) 1834, 10;Festschrift Emil Borel; F. Reinhardt: Basel, 1936; p 375.

  10. Werner, A.Ber. 1914,47, 1954.

    Google Scholar 

  11. Leidié, E.Ann. Chim. Phys. 1889,17, 307.

    Google Scholar 

  12. de la Provostaye, F. H.Ann. Chim. Phys. 1841, 3, 129, 353;1842,4, 453;1842, 5, 47.

    Google Scholar 

  13. Biot, J.-B.Compt. Rend. 1844,19, 719.

    Google Scholar 

  14. Jacques, J.; Collet, A.; Wilen, S. H.,Enantiomers, Racemates, and Resolutions; Wiley-Interscience: New York, 1981; pp 223–240.

    Google Scholar 

  15. Gernez, D.Compt. Rend. 1866,63, 843.

    Google Scholar 

  16. Picard, E.Compt. Rend. 1910,151, 741.

    Google Scholar 

  17. The Times (London), Nov. 1, 1910, p 11d.

  18. Jungfleisch, E.J. Pharm. Chim. 1882,5, 346;

    Google Scholar 

  19. Jungfleisch, E.Bull. Soc. Chim. France 1884,41, 222.

    Google Scholar 

  20. Amiard, G.Bull. Soc. Chim. France 1956, 447.

  21. Secor, R. M.Chem. Rev. 1963,63, 297.

    Google Scholar 

  22. Jordan, C.Compt. Rend. 1916,162, 617.

    Google Scholar 

  23. Léger, E.Bull. Soc. Chim. France 1917,21, 1.

    Google Scholar 

  24. Smith, H. M.Torchbearers of Chemistry; Academic Press: New York, 1949; p 130.

    Google Scholar 

  25. Piutti, A.Ber. 1886,19, 1691.

    Google Scholar 

  26. Ostromisslensky, I.Ber. 1908,41, 3035.

    Google Scholar 

  27. Albrecht, G.; Corey, R. B.J. Am. Chem. Soc. 1939,13, 35.

    Google Scholar 

  28. Iitaka, I.Acta Crystallogr. 1960,13, 35.

    Google Scholar 

  29. Iitaka, I.Acta Crystallogr. 1958,11, 225.

    Google Scholar 

  30. For a detailed review see Addadi, L.; Berkovitch-Yellin, Z.; Weissbuch, I.; Lahav, M.; Leiserowitz, L. In Eliel, E. L.; Allinger, N. L.; Wilen, S. H., Eds.;Topics in Stereochemistry; Wiley: New York, 1986; Vol. 16, pp. 1–86.

    Google Scholar 

  31. Kipping, F. S.; Pope, W. J.J. Chem. Soc. 1887,71, 611.

    Google Scholar 

  32. Werner, A.; Conrad, H. E.Ber. 1899,32, 3046.

    Google Scholar 

  33. Zamboni, F. Z.Kristallogr. Min. 1907,16, 551.

    Google Scholar 

  34. Herpin, P.Compt. Rend. 1958,81, 201.

    Google Scholar 

  35. Pasteur, L. InLeçons de chimie professées en 1860...; Société Chimique de Paris: Paris, 1861; pp 1–48; for an English translation see Pasteur, L.Researches on the Molecular Asymmetry of Natural Organic Products; Alembic Club Reprint No. 14; E. & S. Livingstone: Edinburgh, Scotland, 1948; pp 20–22.

    Google Scholar 

  36. Jaeger, F. M.Proc. Acad. Sci. Amsterdam 1917,20, 263.

    Google Scholar 

  37. For the structure and absolute configuration of (+)-138-01 (δδδ) {[Co(en)3]Cl3}2NaCl·xH2O; see Saito, Y.; Nakatsu, K.; Shiro, M.; Kuroya, H.Bull Chem. Soc. Jpn. 1959,8, 729.

    Google Scholar 

  38. Herpin, P.Compt. Rend. 1958,81, 145.

    Google Scholar 

  39. Jaeger, F. M.; Thomas, W.Proc. Acad. Sci. Amsterdam 1919,22, 693.

    Google Scholar 

  40. Tutton, A. E. H.Crystallography and Practical Crystal Measurements, 2nd ed.; The Indian Printing Works: New Delhi, 1965; reprinted from the original Macmillan, London, 1922, version. See Vol. 2, pp 1282–1283.

    Google Scholar 

  41. Taylor, D.Aust. J. Chem. 1978,31, 1455.

    Google Scholar 

  42. Lis. T.; Matuszewski, J.Acta Crystallogr. Sect B. 1989,36, 1938.

    Google Scholar 

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Bernal, I., Kauffman, G.B. Overlooked opportunities in stereochemistry. Part III: Alfred Werner's awareness of spontaneous resolutions and of the meaning of hemihedral faces in optically active crystals. Struct Chem 4, 131–138 (1993). https://doi.org/10.1007/BF00677373

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