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The dynamics of hydrogen bonds and proton transfer in zeolites – joint vistas from solid-state NMR and quantum chemistry

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Abstract

The different aspects of zeolite Brønsted acid sites are reviewed from the perspective of solid-state NMR spectroscopy and quantum-chemical calculations. The strength of the combined use of these two methods is demonstrated. Special emphasis is dedicated to the structure and dynamics of hydrogen-bonded complexes of zeolites with H2O and CH3OH.

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Authors and Affiliations

  1. Institute of Physical Chemistry, University of Münster, 48149, Münster, Germany

    Hubert Koller

  2. Institute of Chemical Technology I, University of Stuttgart, 70550, Stuttgart, Germany

    Günter Engelhardt

  3. Schuit Institute of Catalysis, Eindhoven University of Technology, 5600 MB, Eindhoven, The Netherlands

    Rutger A. van Santen

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  1. Hubert Koller
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Koller, H., Engelhardt, G. & van Santen, R.A. The dynamics of hydrogen bonds and proton transfer in zeolites – joint vistas from solid-state NMR and quantum chemistry. Topics in Catalysis 9, 163–180 (1999). https://doi.org/10.1023/A:1019131126634

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