Abstract
InGaAsP epitaxial layers, which are obtained in the instability region on InP (001) and GaAs (001) substrates, are investigated by photoluminescence and transmission-electronmicroscopy methods. The results are discussed on the basis of the theory of spinodal decomposition of solid solutions. It is established experimentally that in certain temperature and composition ranges the solid solutions InGaAsP are a system of charged, alternating (in mutually perpendicular directions [100] and [010]) domains of a solid solution with two different compositions and different lattice constants. The domain structure is very clearly defined at the surface of the epitaxial film and becomes blurred in the film near the substrate. The data obtained very likely show spinodal decomposition of the solid solutions InGaAsP in the test samples.
Similar content being viewed by others
References
A. Zunger and S. Mahajan, in Handbook of Semiconductors, edited by T. S. Moss, Vol. 3, edited by S. Mahajan, (Elsevier, 1994) p. 1399.
G. B. Stringfellow, J. Cryst. Growth 58, 194 (1982); G. B. Stringfellow, J. Cryst. Growth 65, 454 (1983).
J. W. Cahn, Trans. Met. Soc. 242, 166 (1967).
A. G. Khachaturyan, Theory of Structural Transformations in Solids (John Wiley and Sons, New York, 1983).
I. P. Ipatova, V. A. Shchukin, V. G. Malyshkin, A. Yu. Maslov, and E. Anastassakis, Solid State Commun. 78, 19 (1991).
M. Ilegems and M. B. Panish, J. Phys. Chem. Solids 35, 409 (1974).
I. S. Tarasov, N. A. Pikhtin, A. V. Murashova, A. V. Lyutetskii, A. Yu. Leshko, M. A. Ivanov, N. A. Bert, and Zh. I. Alfërov, in 2nd Russian Conference on Semiconductor Physics, RKFP’96, Zvenigorod, 1996, Vol. 1, p. 40.
I. S. Tarasov, L. S. Vavilova, N. I. Katsavets, A. V. Lyutetskiy, A. V. Murashova, N. A. Pikhtin, N. A. Bert, and Zh. I. Alferov, in Abstracts International Symposium on Nanostructures: Physics and Technology, St. Petersburg, 1996, p. 362.
I. S. Tarasov, L. S. Vavilova, I. P. Ipatova, A. V. Lyutetskiy, A. V. Murashova, N. A. Pikhtin, V. A. Shchukin, and Zh. I. Alferov, in Proceedings of the 23rd International Symposium on Compound Semiconductors ISCS-23 (St. Petersburg, 1996), 1997, p. 117.
L. S. Vavilova, A. V. Ivanova, V. A. Kapitonov, A. V. Murashova, I. S. Tarasov, I. N. Arsent’ev, N. A. Bert, Yu. G. Musikhin, N. A. Pikhtin, and N. N. Faleev, Fiz. Tekh. Poluprovodn. 32, 658 (1998) [Semiconductors 32, 590 (1998)].
B. de Cremoux, J. Physique 43, C5–19 (1982).
I. P. Ipatova, V. G. Malyshkin, A. Yu. Maslov, and V. A. Shchukin, Fiz. Tekh. Poluprovodn. 26, 285 (1993) [Semiconductors 26, 158 (1993)].
I. P. Ipatova, V. G. Malyshkin, and V. A. Shchukin, J. Appl. Phys. 74, 7198 (1993).
I. P. Ipatova, V. G. Malyshkin, and V. A. Shchukin, Philos. Mag. 70, 557 (1994).
D. Bimbert, I. P. Ipatova, P. S. Kop’ev, N. N. Ledentsov, V. G. Malyshkin, and V. A. Shchukin, Usp. Fiz. Nauk 167(3), 552 (1997).
Seiji Mukai, J. Appl. Phys. 54, 2635 (1983).
Author information
Authors and Affiliations
Additional information
Fiz. Tekh. Poluprovodn. 33, 544–548 (May 1999)
Rights and permissions
About this article
Cite this article
Bert, N.A., Vavilova, L.S., Ipatova, I.P. et al. Spontaneously forming periodic composition-modulated InGaAsP structures. Semiconductors 33, 510–513 (1999). https://doi.org/10.1134/1.1187719
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1134/1.1187719