Skip to main content
SpringerLink
Log in

Extraktionsverhalten von Rutheniumnitrosyl-Komplexen in salpetersauren Lösungen

Extraction behaviour of ruthenium-nitrosyl complexes in nitric acid solutions

  • Originalarbeiten
  • Published:
Fresenius' Zeitschrift für analytische Chemie Aims and scope Submit manuscript

Summary

Solutions of ruthenium-nitrosyl-nitro, ruthenium-nitrosyl-nitro-nitrato and ruthenium-nitrosyl-nitrato complexes can be distinguished clearly from each other by means of paper electrophoresis, extraction chromatography and extractions. The contact time, HNO3-concentration, NO −3 -concentration, HDBP-content of the organic phase and the addition of F−, SO 2−4 , H2PO −4 and C2O 2−4 exert a strong influence on the extraction of the ruthenium-nitrosyl-nitrato complexes with TBP in dodecane.

Zusammenfassung

Lösungen von Rutheniumnitrosylnitro-, Rutheniumnitrosylnitronitrato- und Rutheniumnitrosylnitrato-Komplexen lassen sich mit Hilfe von Papierelektrophorese, Extraktions-Chromatographie und Extraktionen eindeutig voneinander unterscheiden. Kontaktzeit, HNO3-Konzentration, NO −3 -Konzentration, HDBP-Gehalt der organischen Phase und Zusatz von F−, SO 2−4 , H2PO −4 und C2O 2−4 beeinflussen stark die Extraktion der Rutheniumnitrosylnitrato-Komplexe mit TBP in Dodecan.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literatur

  1. Holder JV (1978) Radiochim Acta 25:171

    CAS  Google Scholar 

  2. Kuhn KD, Bähr W (1983) In: Blasewitz AG, Davis JM, Smith MR (eds) The treatment and handling of radioactive wastes. Springer, Heidelberg Berlin New York, p 54

    Google Scholar 

  3. Sperfeld R (1969) Inaugural-Dissertation, Ruprecht-Karl-Universität, Heidelberg

    Google Scholar 

  4. Rühle W (1977) Inaugural-Dissertation, Ruprecht-Karl-Universität, Heidelberg

    Google Scholar 

  5. Pichkov VN, Zvyagintsev OE, Sinitsyn NM (1966) Russ J Inorg Chem 11:1374

    Google Scholar 

  6. Blasius E, Glatz J-P, Neumann W (1981) Radiochim Acta 29:159

    CAS  Google Scholar 

  7. Blasius E, Müller K, Wagner H (1982) Fresenius Z Anal Chem 311:192

    Article  CAS  Google Scholar 

  8. Blasius E, Müller K, Wagner H (1983) Fresenius Z Anal Chem 315:448

    Article  CAS  Google Scholar 

  9. van Ooyen J, Bac R, Bonnevie-Svendsen M, Eschrich H (Aug. 1964) Proceedings of the Third International Conference on the Peaceful Uses of Atomic Energy, Vol 10, Geneva, 404

  10. Siczek AA, Steindler MJ (1978) Atomic Energy Review 16:575

    CAS  Google Scholar 

  11. Herforth L, Koch H (1975) Praktikum der angewandten Radioaktivität, VEB Deutscher Verlag der Wissenschaften, Berlin

    Google Scholar 

  12. Lederer M, Shukla SK (1961) J Chromatog 6:429

    Article  CAS  Google Scholar 

  13. Fries J, Getrost H (1975) Organische Reagenzien für Spurenanalyse, E. Merck, Darmstadt

    Google Scholar 

  14. Sawicki CR, Scaringelli FP (1971) Microchem J 16:657

    Article  CAS  Google Scholar 

  15. Ayres GH, Young F (1950) Anal Chem 22:1277

    Article  CAS  Google Scholar 

  16. Ayres GH, Young F (1950) Anal Chem 22:1281

    Article  CAS  Google Scholar 

  17. Lingane PJ (1969) Anal Chim Acta 47:529

    Article  CAS  Google Scholar 

  18. Welz B (1975) Atomabsorptionsspektroskopie, Verlag Chemie, Weinheim

    Google Scholar 

  19. Hallaba E, Azzam RAI (1962) Z Anorg Chem 314:53

    Article  CAS  Google Scholar 

  20. Pruett DJ (1980) Radiochim Acta 27:115

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Fachrichtung Anorganische Analytik und Radiochemie der Universität des Saarlandes, 6600, Saarbrücken, Bundesrepublik Deutschland

    E. Blasius, H. J. Luxenburger & W. Neumann

Authors
  1. E. Blasius
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. H. J. Luxenburger
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. W. Neumann
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Für finanzielle Unterstützung danken wir dem Bundesminister für Forschung und Technologie, Bonn-Bad Godesberg.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Blasius, E., Luxenburger, H.J. & Neumann, W. Extraktionsverhalten von Rutheniumnitrosyl-Komplexen in salpetersauren Lösungen. Z. Anal. Chem. 319, 38–46 (1984). https://doi.org/10.1007/BF00476227

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00476227

Search

Navigation