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Synthesis and characterization of poly(arylene ether sulfone)s with pendant amines on the main chain

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Summary

Synthesis of poly(arylene ether sulfone)s with random incorporation of pendant aryl amines was achieved by copolymerization of dichlorodiphenylsulfone (DCDPS) and bisphenol-A with bis(4-fluorophenyl)-3-aminophenylphosphine oxide (amino DFTPPO) with N-methylpyrrolidone (NMP) as the solvent, toluene as the azeotrope and potassium carbonate (K2CO3) as the weak base. A unique feature of this polymerization is that one of the comonomer (amino DFTPPO) contains both an amine functionality as well as activated dihalides which can undergo aromatic nucleophilic displacement by the phenolate, the degree of amination on the main chain can be controlled very precisely by regulating the amount of the amino DFTPPO monomer relative to the other activated dihalide monomer (DCDPS) and bisphenol-A. The synthesis and characterization of poly(arylene ether sulfone)s with various concentration of amine groups on the backbone will be discussed in this paper.

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Authors and Affiliations

  1. Department of Chemistry and NSF Science and Technology, High Performance Polymeric Adhesives and Composites, Virginia Polytechnic Institute and State University, 24061-0212, Blacksburg, VA

    S. J. Pak, G. D. Lyle, R. Mercier & J. E. McGrath

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  1. S. J. Pak
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  2. G. D. Lyle
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  3. R. Mercier
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  4. J. E. McGrath
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Pak, S.J., Lyle, G.D., Mercier, R. et al. Synthesis and characterization of poly(arylene ether sulfone)s with pendant amines on the main chain. Polymer Bulletin 29, 477–484 (1992). https://doi.org/10.1007/BF00296707

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  • DOI: https://doi.org/10.1007/BF00296707

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