Summary
The usage of the Complete Flame Ionisation Detector enables simultaneous depicting of two responses of the flame. Simultaneous registering on two high speed recorders enables a specific record of chloride organic materials as for instance chlorate hydrocarbon. In this way artificial mixtures containing Methane, Pentane, Cyclohexane, Acetylacetoacetic ester, Ethyl acetate, Carbon tetrachloride, Methyl alcohol, Methylene chloride, Ethylalcohol, Benzene, Trichlorethylene, Chloroform, Tetrachlorethylene, Toluene, 1,2-Dichlorethane, Isoamyl acetate were analysed. Practical examples show the possibility of using the described method.
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Literatur
Harrison, G. T.: Vapour phase chromatographic analysis of chlorinated hydrocarbons and hydrocarbon gases. I. Symposium on PVC, London (D. H. Desty, Butterworths Sci., Publ.) 1956.
Waren, G. W., L. J. Priestley, J. F. Haskin, andV. A. Yarborough: Gas chromatographic analysis of mixtures of chlorine compounds. Anal. Chem.31, 1013 (1959).
Chundela, B., u.J. Janák: Gaschromatographie und ihre Anwendung in der toxikologischen Analyse. Soud. Lék.5, 104–110 (1960).
— — u.J. Lukači: Vergiftung mit 1,2-Dichlorethan. Soud. Lék.8, 3–7 (1963).
Janota, M., andB. Chundela: Acute intoxication with Dichlorethane. Pracov. Lék.16, 69–72 (1964).
Hasegawa, K., S. Seno, andM. Moriuchi: Gas chromatographic determination of chloroform in pharmaceutical preparation. Japan Analyst15, 179–180 (1966).
Barker, P. E., andD. H. Huntington: The preparative scale separation of multicomponent mixtures by continuous gas liquid chromatography. J. Gas Chromatogr.4, 59–66 (1966).
Chundela, B., andJ. Janák: Quantitative determination of ethanol besides other substances in blood and other body liquids by gas chromatography. J. forens. Med.7, 153–161 (1960).
Machata, G.: Über die gaschromatographische Blutalkoholbestimmung. Analyse der Dampfphase. Mikrochim. Acta1964, 262–271.
Škrabánek, P., u.J. Novák: Bestimmung des Blutäthylalkohols mittels der Gaschromatographie. Blutalkohol3, 271–277 (1966).
Fox, J. E.: Gaschromatographic Analysis of alcohol and certain others volatiles in biological material for forensic purposes. Proc. Soc. exp. Biol. (N.Y.)97, 236–237 (1958).
McCord, W. M., andR. H. Gadsden: The identification and determination of alcohols in blood by gas chromatography. J. Gas Chromatogr.2, 38–39 (1964).
Ginffrida, L., andF. Ives: J. Ass. Off. Agric. Chem.47, 293 (1964).
Karmen, A.: Specific detection of halogens and phosphorus by flame ionization. Anal. Chem.36, 1416–1421 (1964).
Janák, J., and V.Svojanovský: Working properties of a coupled flame ionization — sodium thermoionic detector. Sixth Internat. Symposium on Gas Chromatography and Associated Techniques. (Roma, 20–23th Sept. 1966.)
Cremer, E., H. Moesta, u.K. Hablick: Zur Anwendung des thermoionischen Halogen-Detektors in der Gas-Chromatographie. Chemie Ing.-Techn.38, 580–583 (1966).
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Vorgetragen auf der Tagung der Deutschen Gesellschaft für gerichtliche und soziale Medizin in Freiburg i. Br., Oktober 1966.
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Chundela, B., Krejćí, M. & Rusek, M. Einige Möglichkeiten der Verwendung des Zweibrennerflammendetektors zur Bestimmung chlorierter organischer Stoffe in der Toxikologie. Dtsch. Z. ges. gerichtl. Med. 63, 154–161 (1968). https://doi.org/10.1007/BF00584598
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DOI: https://doi.org/10.1007/BF00584598