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Verhalten von 7-Methoxy-neopinondimethylacetal-methoperchlorat gegenüber Säure

Behaviour of 7-methoxy-neopinone dimethyl acetal-methoperchlorate in acidic solution

  • Organische Chemie und Biochemie
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Monatshefte für Chemie - Chemical Monthly Aims and scope Submit manuscript

Abstract

Dependent on reaction conditions acidic hydrolysis of 7-methoxy-neopinone-dimethylacetal-methoperchlorate (1) yields Δ8(14)-7-oxo-metathebainone-methoperchlorate (9), 7-methoxy-7.8-dehydro-metathebainone-methoperchlorate (13 a) or 7-hydroxy-morphothebaine-methoperchlorate (14), resp.

Zusammenfassung

Saure Hydrolyse von 7-Methoxy-neopinondimethylacetal-methoperchlorat (1) liefert je nach Reaktionsbedingungen Δ8(14)-7-Oxo-metathebainon-methoperchlorat (9), 7-Methoxy-7.8-dehydro-metathebainon-methoperchlorat (13 a) oder 7-Hydroxy-morphothebain-methoperchlorat (14).

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Authors and Affiliations

  1. Pharmazeutisch-Chemischen Institut der Universität Wien, Wien, Österreich

    G. Heinisch & F. Vieböck

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  1. G. Heinisch
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  2. F. Vieböck
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Herrn Prof. Dr.M. Pailer zum 60. Geburtstag gewidmet.

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Heinisch, G., Vieböck, F. Verhalten von 7-Methoxy-neopinondimethylacetal-methoperchlorat gegenüber Säure. Monatshefte für Chemie 102, 770–774 (1971). https://doi.org/10.1007/BF01167258

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  • DOI: https://doi.org/10.1007/BF01167258

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