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Die anodisch angeregte kationische Polymerisation von Isobutylvinyläther

The anodically initiated cationic polymerization of isobutyl vinyl ether

  • Anorganische, Struktur- und Physikalische Chemie
  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

At low current intensities with tetraethylammonium perchlorate as supporting electrolyte a stationary cationic polymerization of isobutyl vinyl ether in an acetonitrile-diisopropyl ether solvent is obtained at the platinum anode. The electrochemical and kinetic characteristics of the system are determined. An influence of water is found. The molecular weight of the polymer is mainly given by chain transfer to the monomer.

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Authors and Affiliations

  1. Institut für Physikalische Chemie, Universität Wien, Währinger Straße 42, A-1090, Wien, Österreich

    Johann Wolfgang Breitenbach, F. Sommer & G. Unger

Authors
  1. Johann Wolfgang Breitenbach
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  2. F. Sommer
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  3. G. Unger
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Gegenwärtige Adresse: Semperit AG, A-2514 Traiskirchen.

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Breitenbach, J.W., Sommer, F. & Unger, G. Die anodisch angeregte kationische Polymerisation von Isobutylvinyläther. Monatshefte für Chemie 107, 359–366 (1976). https://doi.org/10.1007/BF00906863

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  • DOI: https://doi.org/10.1007/BF00906863

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