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Darstellung und Röntgenstrukturanalyse von 26 Thiomolybdato- bzw. Thiowolframato-und eines Selenowolframato-Komplexes

Preparation and X-ray structure analysis of 26 thiomolybdato, thiotungstato, and of one selenotungstato complex

  • Anorganische Und Physikalische Chemie
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Summary

The preparation and characterization by X-ray structure analysis of the following chalcogenometalato complexes are reported:

1: [(Ph 3P)2N]2(NEt 4)[Fe(WS4)2]·2MeCN;

2: [(Ph 3P)2N]2(NEt 4)[Cu(WS4)2]·2MeCN;

3: [(Ph 3P)2N]2(NEt 4)[Ag(MoS4)2]·MeCN;

4: [(Ph 3P)2N]2(NEt 4)[Ag(WS4)2]·MeCN;

5: (PPh 4)2[Hg(WS4)2];

6: (PPh 4)2[Au2(WOS3)2];

7: (PPh 4)4[Pb2(MoS4)4];

8: (PPh 4)4[Pb2(WS4)4];

9: (NEt 4)2[Fe(WS4)2(H2O)2];

10: [Fe(DMSO)6][Cl2Fe(MoS4)];

11: [Fe(DMSO)6][Cl2Fe(MoOS3)];

12: (PPh 4)(NMe 3CH2 Ph)[Cl2Fe(WS4)];

13: [Fe(DMF)6][Cl2Fe(WS4)];

14: (PPh 4)2[Cl2Fe(WS4)];

15: (PPh 4)2[Cl2Fe(WS4)]·2 CH2Cl2;

16: (PPh 4)2[NCCu(MoS4)];

17: (PPh 4)2[NCAg(MoS4)];

18: (PPh 4)2[NCAg(WS4)];

19: (PPh 4)2[Cu3Cl3(MoOS3)];

20: (PPh 4)2[Cu3Br3(MoS4)]·MeCN;

21: (PPh 3)3Cu2(MoOS3)·0.8 CH2Cl2;

22: (PPh 3)3Cu2(WOS3)·0.8 CH2Cl2;

23: {Cu3MoS3Br}(PPh 3)3O·0.5Me 2CO;

24: (PPh 3)3Ag2(WSe4)·0.8 CH2Cl2;

25: [(Ph 3P)2N]2(NEt 4)2[Fe2S2(WS4)2]·3MeCN;

26: (PPh 4)2[MoO(MoS4)2];

27: (PPh 4)2[Br2Fe(WOS4)]·DMF.

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Authors and Affiliations

  1. Fakultät für Chemie, Universität Bielefeld, D-4800, Bielefeld 1, Bundesrepublik Deutschland

    Achim Müller, Hartmut Bögge, Uwe Schimanski, Michael Penk, Katrin Nieradzik, Mechtild Dartmann, Erich Krickemeyer, Jürgen Schimanski, Christian Römer, Michael Römer, Horst Dornfeld, Ulf Wienböker, Winfried Hellmann & Marion Zimmermann

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  1. Achim Müller
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Müller, A., Bögge, H., Schimanski, U. et al. Darstellung und Röntgenstrukturanalyse von 26 Thiomolybdato- bzw. Thiowolframato-und eines Selenowolframato-Komplexes. Monatsh Chem 120, 367–391 (1989). https://doi.org/10.1007/BF00811550

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