Summary
The structure and packing of the lattice of the compounds (PPh4)3[As(CS3)3] (1), (PPh4)3[Bi(CS3)3] (2), and (PPh4)3[Fe(CS3)3]·H2O (3) is discussed in terms of hostguest chemistry in a “soft” matrix of large cations. The hitherto unknown Fe-complex was characterized by elemental analysis and single crystal structure analysis. Here CS 2−3 acts as a classical bidentate ligand, whereas in the case of the arsenic and bismut complexes, the coordination of this ligand is essentially unidentate due to an interaction with the lone pair on the central atom. For the last two complexes, there seems to be an influence of the packing on the coordination geometry.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literatur
vgl. Lehn JM (1992) In: Williams AF, Floriani C, Merbach AE (eds) Perspectives in coordination chemistry. VCH, Weinheim, S447 sowie Lehrbücher der Anorganischen und Strukturchemie
Gattow G, Behrendt W (1977) In: Senning A (ed) Topics in sulfur chemistry, vol 2. Thieme Stuttgart, S154f; Coucouvanis D (1979) Progr Inorg Chem26: 301f; Livingstone SE (1987) In: Wilkinson G, Gillard RD, McCleverty JA (eds) comprehensive coordination chemistry, vol 2. Pergamon, Oxford, S633f; Cras JA, Willemse J ibid.: 579f
Müller A, Reuter H, Dillinger S (1995) Angew Chem107 (im Druck); Reuter H (1992) Angew Chem104: 1210; Angew Chem Int Ed Engl31: 1185
Müller A, Krickemeyer E, El-Katri F, Rehder D, Stammler A, Bögge, H, Hellweg F (1995) Z Anorg Allg Chem621: 1160
Deskin WA (1958) J Am Chem Soc 80: 5680; Fackler Jr JP, Coucouvanis D (1966) J Am Chem Soc88: 3913
McAuliffe CA (1987) In: Wilkinson G, Gillard RD, McCleverty JA (eds) Comprehensive coordination chemistry, vol. 3. Pergamon, Oxford, S237f und die dort zitierte Literatur
Biltz W (1932) Raumchemie der festen Stoffe. Voß. Leipzig
Ahlborn E, Diemann E, Müller A (1972) J Chem Soc Chem Comm 378; Ahlborn E, Diemann E, Müller A (1972) Z Anorg Allg Chem394: 1; Ahlborn E, Diemann E, Müller A (1972) Z Naturforsch 27b: 1108; Königer-Ahlborn E, Müller A (1975) Angew Chem87: 599; (1975) Angew Chem Int Ed Engl14: 574; Königer-Ahlborn E, Müller A (1976) Z Naturforsch31b:1429; Diemann E, Müller A (1976) Z Naturforsch31b: 1287; Königer-Ahlborn E, Schulze H, Müller A (1977) Z Anorg Allg Chem428: 5; vgl. auch Behrends K, Kiel G (1969) Z Anal Chem247: 16
Müller A, Diemann E, Bollmann F (1968) Naturwissenschaften55: 443; Diemann E, Ahlborn E, Müller A (1972) Z Anorg Allg Chem390: 217
Author information
Authors and Affiliations
Additional information
Herrn Prof. Dr.E. Hengge zum 65. Geburtstag gewidmet
Rights and permissions
About this article
Cite this article
Müller, A., Diemann, E., Krickemeyer, E. et al. Bemerkenswerte Wirt-Gast-Beziehungen in Tetraphenylphosphoniumsalzen vontris-Trithiocarbonato-Komplexen des As(III), Bi(III) und Fe(III). Monatsh Chem 127, 43–49 (1996). https://doi.org/10.1007/BF00807407
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00807407