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Kristallstruktur von Na3(NH4)12[Mo57Fe6(NO)6O174(OH)3(H2O)24]·76H2O, einer Verbindung mit einem ungewöhnlichen Clusteranion

Crystal structure of Na3(NH4)12[Mo57Fe6(NO)6O174(OH)3(H2O)24]·76H2O, a compound with an unique cluster anion

  • Anorganische Und Physikalische Chemie
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Summary

The X-ray crystal structure of the compound Na3(NH4)12[Mo57Fe6(NO)6O174(OH)3(H2O)24]·76H2O (3) [P63/mmc;a=2380.6(5),c=2763.4(7),Z=2], the giant cluster anion of which has the shape of a doughnut, shows remarkable details: The cluster [{Fe(H2O)2}6{Mo(μ-H2O)2(μ-OH)Mo}3{ Mo15(MoNO) 3+2 O58(H2O)2}3]15− can be described as being composed of three transferable {Mo17} ligands bridged by cationic centers and contains a novel nanodimensional central cavity.

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Literatur

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Authors and Affiliations

  1. Lehrstuhl für Anorganische Chemie I, Fakultät für Chemie der Universität, D-33501, Bielefeld, Bundesrepublik Deutschland

    A. Müller, W. Plass, E. Krickemeyer, S. Dillinger, H. Bögge, A. Armatage, C. Beugholt & U. Bergmann

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  1. A. Müller
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  2. W. Plass
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  3. E. Krickemeyer
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  4. S. Dillinger
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  5. H. Bögge
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  6. A. Armatage
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  7. C. Beugholt
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  8. U. Bergmann
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Müller, A., Plass, W., Krickemeyer, E. et al. Kristallstruktur von Na3(NH4)12[Mo57Fe6(NO)6O174(OH)3(H2O)24]·76H2O, einer Verbindung mit einem ungewöhnlichen Clusteranion. Monatsh Chem 125, 525–533 (1994). https://doi.org/10.1007/BF00811844

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  • DOI: https://doi.org/10.1007/BF00811844

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