Skip to main content
SpringerLink
Log in

Mechanical properties and molecular mobility in oriented polyolefines

  • Polymer Science
  • Published:
Colloid and Polymer Science Aims and scope Submit manuscript

Abstract

The static modulus of elasticity (E) and the correlation time of rotation (τ c ) of 2,-2,6,6-tetramethylpiperidine-1-oxyl are studied as a function of the temperature (210<T <350°K) for oriented films of isotactic polypropylene and polyethylene of high and low density.E andτ c change both upon heating and polymer orientation; this result indicates that sample properties are influenced by the microstructure of the amorphous phase where probes are localized.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Glenz W, Morosoff N, Peterlin A (1971) J Polym Sci B9:211

    Article  Google Scholar 

  2. Meinel G, Peterlin A (1968) J Polym Sci A2 6:587

    Article  CAS  Google Scholar 

  3. Peterlin A (1974) Pure Appl Chem 39:239

    Article  CAS  Google Scholar 

  4. Peterlin A (1977) J Appl Phys 48:4099

    Article  CAS  Google Scholar 

  5. Gubanov AI (1966) Mekh Polimerov 1:143

    Google Scholar 

  6. Egorov EA, Zhizhenkov W (1968) Vysokomolek soed A, 10:451

    CAS  Google Scholar 

  7. Egorov EA, Zhizhenkov VV (1982) J Polym Sci, Polym Phys Ed, 20:1089

    Article  CAS  Google Scholar 

  8. Zhizhenkov W, Egorov EA (1984) J Polym Sci Polym Phys Ed, 22:117

    Article  CAS  Google Scholar 

  9. Peschanskaya NN, Stepanov VA (1971) Mekh Polimerov 1:30

    Google Scholar 

  10. Egorov EA, Peschanskaya NN, Stepanov VA (1969) Fiz tv tela 11:1325

    CAS  Google Scholar 

  11. de Candia F, Russso R, Vittoria V, Peterlin A (1982) J Polym Sci Phys Ed 20:269

    Article  Google Scholar 

  12. Kuznetsov AN (1976) The Spin Probe Method Nauka

  13. Kovarskii AL, Placek I, Szoks F (1978) Polymer 19:1137

    Article  CAS  Google Scholar 

  14. Araimo L, de Candia F, Vittoria V, Peterlin A (1978) J Polym Sci, Polym Phys Ed 16:2087

    Article  CAS  Google Scholar 

  15. Barashkova II, Vasserman AM, Rappoport NYa (1979) Vysokomolek soed, 21A:1683

    Google Scholar 

  16. Krisyuk BE, Griva AP, Denisov ET, Popov AA (1982) Spin Probe Behaviour in Polymers Under Stresss. Preprint, Chernogolovka: OIKhF AN SSSR Press

    Google Scholar 

  17. de Candia F, Russo R, Vittoria V, Krisyuk BE, Popov AA, Zaikov GE (1986) Polymer 27:1743

    Article  Google Scholar 

  18. Krisyuk BE, Rogov YuN, Griva AP, Denisov ET (1982) Vysokomolek soed B24:634

    Google Scholar 

  19. Peterlin A (1979) (ed) Ciferri A, Ward IM, Ultra high modulus polymers, Applied Science, Barking England

    Google Scholar 

  20. de Candia F, Botta A, Vittoria V (1986) J Polym Sci, Phys Ed 24:2145

    Article  Google Scholar 

  21. Takayanagi M, Imada K, Kajiyama T (1966) J Polym Sci, C15:263

    Google Scholar 

  22. Verkhovetz AP (1980) Vysokomolek soed B22:246

    Google Scholar 

  23. Sakurada I, Ito T, Nakamae K (1966) J Polym Sci C15:75

    Google Scholar 

Download references

Author information

Author notes

  1. F. de Candia

    Present address: Institute of Technology and Rheology of Polymers, Arco Felice, Napoli, Italy

Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences, Moscow, USSR

    B. E. Krisyuk, A. A. Popov, G. E. Zaikov, F. de Candia, V. Vittoria & R. Russo

  2. Institute of Technology and Rheology of Polymers, Arco Felice, Napoli, Italy

    V. Vittoria & R. Russo

Authors
  1. B. E. Krisyuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. A. Popov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. E. Zaikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. F. de Candia
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. Vittoria
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. R. Russo
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Krisyuk, B.E., Popov, A.A., Zaikov, G.E. et al. Mechanical properties and molecular mobility in oriented polyolefines. Colloid & Polymer Sci 265, 220–225 (1987). https://doi.org/10.1007/BF01412710

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01412710

Key words

Search

Navigation