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Free radical copolymerization of 1-vinyl naphthalene with styrene, methyl methacrylate, and acrylonitrile

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Abstract

Investigations on free radical copolymerization of 1-vinyl naphthalene (1-VNph, monomerM 2) with styrene (St), methyl methacrylate (MMA) and acrylonitrile (AN) (monomersm 1) in bulk at 60°C with AIBN as initiator are presented. Relative reactivity ratios were calculated by the Kelen-Tüdös method yielding:r st=0.70 ±0.23 andr 1−VNph=2.02 ±0.40 for system St/1-VNph;r MMA=0.32 ±0.10 andr 1−VNph=0.57 ±0.07 for system MMA/1-VNph andr AN=0.11 ±0.03 andr 1−VNph=0.45 ±0.09 for system AN/1-VNph.Q, e values for 1-VNph according to Alfrey, Price scheme were calculated toQ 1−VNph=1.02,e 1−VNph=−0.62.

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  1. D. Braun

    Present address: Deutsches Kunststoff-Institut, Darmstadt, Germany

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    1. D. Braun
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    2. A. Essmail Pour
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    3. W. K. Czerwinski
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    Braun, D., Essmail Pour, A. & Czerwinski, W.K. Free radical copolymerization of 1-vinyl naphthalene with styrene, methyl methacrylate, and acrylonitrile. Colloid & Polymer Sci 267, 1096–1100 (1989). https://doi.org/10.1007/BF01496929

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