Skip to main content
Log in

Experimental results for the L3 phase in a zwitterionic surfactant system and their implications regarding structures

  • Colloid Science
  • Published:
Colloid and Polymer Science Aims and scope Submit manuscript

Abstract

Conditions for existence of the L3 phase have been determined for a system containing water, n-hexanol, and the zwitterionic surfactant n-tetradecyldimethylamineoxide. Electric birefringence, light-scattering, rheology, and electrical-conductivity experiments were performed on this phase. Results are consistent with the existence of platelike micelles, whose diameter changes with surfactant concentration in such a way that it remains comparable to mean plate spacing. This behavior can be understood in terms of a previous L3 phase theory containing randomly oriented plates.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Miller CA, Ghosh O, Benton WJ (1986) Colloids and surfaces 19:197

    Google Scholar 

  2. Porte G, Gomati R, El Hartanie O, Appell J, Marignan J (1987) J Phys Chem 91:6203

    Google Scholar 

  3. Mitchell DJ, Tiddy GJT, Warreng L, Bosteck T, Mc Donald MP (1983) J Chem Soc Faraday Trans 179:915

    Google Scholar 

  4. Marginan J, Gauthier-Fournier F, Appell J, Akoum F, Lang J (1988) J Phys Chem 92:440

    Google Scholar 

  5. Olsson U, Shinoda K, Lindman B (1986) J Phys Chem 90:4083

    Google Scholar 

  6. Findenegg GH, Hirtz A, Rasch R, Sowa F (1989) J Phys Chem 93:4580

    Google Scholar 

  7. Nilsson PG, Lindman B (1984) J Phys Chem 88:4764

    Google Scholar 

  8. Anderson D, Wennerström H, Olsson U (1989) J Phys Chem 93:4243

    Google Scholar 

  9. Porte G, Marignan J, Bassereau P, May R (1989) J Physique 49

  10. Miller CA, Ghosh O (1986) Langmuir 2:321

    Google Scholar 

  11. Hoffmann H, Oetter G, Schwandner B (1987) Progr Colloid Polymer Sci 73:95

    Google Scholar 

  12. Ekwall P (1975) Adv Liquid Crystals Brown GH (ed) 1:1

  13. Morris VJ, Foweraker AR, Jennings BR (1978) Adv Mol Processes 12:65, 201–211

    Google Scholar 

  14. Doi M, Edwards SF (1978) J Chem Soc Faraday Trans II 74:560

    Google Scholar 

  15. Thurn H, Löbl M, Hoffmann H (1985) J Phys Chem 89:517

    Google Scholar 

  16. Kerker M (1969) The Scattering of Light and Other Electromagnetic Radiation. Academic Press, New York

    Google Scholar 

  17. Cates ME, Roux D, Andelman D, Milner ST, Safran SA (1988) Europhys Lett 5:733

    Google Scholar 

  18. Onsager L (1949) Ann NY Acad Sci 51:627

    Google Scholar 

  19. Forsyth (1978) Adv Colloid Interface Sci 9:37

    Google Scholar 

  20. Cates ME, Roux D, Andelman D, Milner ST, Safran SA, (1988) Europhysics Letters 5(8):733

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

on leave from Rice University, Texas, USA

Rights and permissions

Reprints and permissions

About this article

Cite this article

Miller, C.A., Gradzielski, M., Hoffmann, H. et al. Experimental results for the L3 phase in a zwitterionic surfactant system and their implications regarding structures. Colloid & Polymer Sci 268, 1066–1072 (1990). https://doi.org/10.1007/BF01410596

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01410596

Key words

Navigation