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Investigation of interaction of olefin-bonded transition metal complexes by gas chromatography. Diphenylphosphine complexes with CoCl2 and CoBr2

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Summary

Packings consisting of diphenylphosphine complexes with CoCl2 and CoBr2, chemically bonded to the silica surface, were synthesized and their retention parameters determined. The packings are capable of specifically interacting with electron-donating compounds by forming π-complexes. The interaction is considerably stronger in the case of CoBr2-containing packing than in the case of CoCl2-containing packing.

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Authors and Affiliations

  1. Department of Chemistry, A. Mickiewicz University, Grunwaldzka 6, 60-780, Poznań, Poland

    W. Wasiak & W. Szczepaniak

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  1. W. Wasiak
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  2. W. Szczepaniak
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Wasiak, W., Szczepaniak, W. Investigation of interaction of olefin-bonded transition metal complexes by gas chromatography. Diphenylphosphine complexes with CoCl2 and CoBr2 . Chromatographia 18, 205–210 (1984). https://doi.org/10.1007/BF02276734

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  • DOI: https://doi.org/10.1007/BF02276734

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