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On-column injection in the stopped-flow mode with open-tubular columns

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Summary

A simple, inexpensive, on-column injector of the septum moving-needle kind is described for quantitative analysis using open-tubular columsn. when operated in the stopped-flow mode an improvement incolumn efficiency is observed combined wit a diminished tendency to produce split-top peaks, particularly for late eluting peaks. Using electronic integration a relative error of about 2.7% was observed for peaks spanning a wide range of sample concentrations and volatilities.

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References

  1. K. Grob, J. High Res. Chromatogr.2, 263 (1978).

    Google Scholar 

  2. V. Pretorius, K. Lawson, W. Bertsch, J. High. Res. Chromatogr.6, 185 (1983).

    Google Scholar 

  3. G. Schomburg, H. Husmann, F. Schulz, J. High Res. Chromatogr.5, 565 (1982).

    Google Scholar 

  4. K. Grob, H. P. Neukom, J. Chromatogr.236, 297 (1982).

    Google Scholar 

  5. J. Eyem, J. Chromatogr.217, 99 (1981).

    Google Scholar 

  6. K. Grob, H. P. Neukom, P. Hilling, J. High Res. Chromatogr.4, 203 (1981).

    Google Scholar 

  7. W. G. Jennings, Sample Preparation for Gas chromatographic Analysis, Huthig, Heidelberg, 1983, p. 5.

    Google Scholar 

  8. R. Jenkins, W. Jennings, J. High Res. Chromatogr.6, 228 (1983).

    Google Scholar 

  9. V. Pretorius, C. S. G. Phillips, W. Bertsch, J. High Res. Chromatogr.6, 232 (1983).

    Google Scholar 

  10. K. Grob, B. Schilling, J. Chromatogr.260, 265 (1983).

    Google Scholar 

  11. K. Grob, P. Neukom, J. Chromatogr.189, 109 (1980).

    Google Scholar 

  12. M. Galli, S. Trestianu, J. Chromatogr.203, 193 (1981).

    Google Scholar 

  13. G. Schomburg, H. Husmann, R. Rittmann, J. Chromatogr.204, 85 (1981).

    Google Scholar 

  14. K. Grob, J. Chromatogr.213, 3 (1981).

    Google Scholar 

  15. M. Galli, S. Trestianu, K. Grob, J. High Res. Chromatogr.2, 366 (1979).

    Google Scholar 

  16. W. G. Jennings, G. Takeoka, Chromatographia,15, 1886 (1982).

    Google Scholar 

  17. F.-S. Wang, H. Shanfield, A. Zlatkis, Anal. Chem.54, 1886 (1982).

    Google Scholar 

  18. F.-S. Wang, H. Shanfield, A. Zlatkis, J. High Res. Chromatogr.5, 562 (1982).

    Google Scholar 

  19. L. Ghaoui, F.-S. Wang, H. Shanfield, A. Zlatkis, J. High Res. Chromatogr.6, 497 (1983).

    Google Scholar 

  20. A. Zlatkis, F.-S. Wang, H. Shanfield, Anal. Chem.55, 1848 (1983).

    Google Scholar 

  21. M. W. Ogden, H. M. McNair, J. High Res. Chromatogr.6, 550 (1983).

    Google Scholar 

  22. J. V. Hinshaw, F. S. Yang, J. High Res. Chromatogr.6, 554 (1983).

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Wayne State University, 48202, Detroit, MI, U.S.A.

    F. Pacholec & C. F. Poole

Authors
  1. F. Pacholec
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  2. C. F. Poole
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Dedicated to Professor A. Zlatkis on the occastion of his 60th birthday.

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Pacholec, F., Poole, C.F. On-column injection in the stopped-flow mode with open-tubular columns. Chromatographia 18, 234–238 (1984). https://doi.org/10.1007/BF02270556

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  • DOI: https://doi.org/10.1007/BF02270556

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