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Resolution and assignment of the configuration of secondary aliphatic alcohols by gas chromatography on chiral phase

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The study of the resolution of sixteen secondary aliphatic alcohols by gas chromatography on (+)-dodecyl (2R, 3R)-tartrate, trapping the ascending part of the peak from a conventional filled column, has allowed the determination in a single operation of the sign and order of emergence of enantiomers. A correlation between the configuration of these secondary alcohols and their order of emergence has been established.

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Binet, S., Dreux, J. & Longeray, R. Resolution and assignment of the configuration of secondary aliphatic alcohols by gas chromatography on chiral phase. Chromatographia 18, 294–296 (1984). https://doi.org/10.1007/BF02259080

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  • DOI: https://doi.org/10.1007/BF02259080

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