metal-organic compounds
The crystal structure of the title complex, [Cu{ONC(CN)2}(C12H8N2)2(H2O)][ONC(CN)2], is composed of discrete [Cu(dcnm)H2O(phen)2]+ cations and dcnm anions [phen is 1,10-phenanthroline and dcnm is dicyanonitrosomethanide, ONC(CN)2-]. The coordination polyhedron of the CuII atom is a distorted elongated tetragonal bipyramid with a CuN4O2 chromophore. The water molecule occupies an axial position, while the dcnm anion occupies an equatorial position.
Supporting information
Crystallographic Information File (CIF) | |
Structure factor file (CIF format) |
CCDC reference: 129795