ESR spectrum of selenium atoms in the gas phase and calculation of g-values including configuration interaction effects

doi:10.1016/0009-2614(72)85077-2

Chemical Physics Letters

Volume 13, Issue 3, 1 March 1972, Pages 325-327

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Abstract

Results from ESR experiments on atomic selenium vapour in the ³P₂ ground state are given. The observed g-value and hyperfine constant of the ⁷⁷Se isotope are 1.49137(4) and 545.7(5) MHz, respectively.

A calculation of g-values based on the Russell-Saunders coupling scheme and taking configuration interaction to second order into account, is applied to p² and p⁴ configurations. The results for Se, Te, Ge and Sn show good agreement with experiment.

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ESR spectrum of selenium atoms in the gas phase and calculation of g-values including configuration interaction effects

Abstract

Chem. Phys. Letters

Phys. Rev.

Ber. Bunsenges. Physik. Chem.

Phys. Rev.

Phys. Rev.