Zeeman splittings of the two lowest excited states of [Ru(bpy)3](PF6)2
References (21)
- et al.
Inorg. Chem.
(1984) - et al.
J. Am. Chem. Soc.
(1988) - et al.
J. Am. Chem. Soc.
(1984) - et al.
J. Phys.
(1985) - et al.
XI IUPAC Symposium on Photochemistry, Lisbon
(1986) - et al.
Chem. Phys. Letters
(1989) - et al.
J. Chem. Phys.
(1973)et al.Chem. Phys.
(1974) Chem. Phys. Letters
(1987)- et al.
Progr. Inorg. Chem.
(1989) - et al.
J. Am. Chem. Soc.
(1981)
Cited by (14)
Ultrafast relaxation dynamics of amine-substituted bipyridyl ruthenium(II) complexes
2017, Chemical Physics LettersCitation Excerpt :For ruthenium(II) polypyridyl complexes, the highest occupied molecular orbitals (HOMOs) are usually localized on the t2 orbital of ruthenium, while the lowest unoccupied molecular orbitals (LUMOs) have dominant contributions of the π∗ orbital of auxiliary ligands. The excited-state electron appears to be delocalized on all ligands in the initial 1MLCT excited-state followed by the charge localization onto the lowest-energy ligand [18–21]. Heteroleptic ruthenium(II) complexes exhibit complex photophysical properties because of the additional ligand-to-ligand charge-transfer transition (LLCT), and the interligand electron transfer is almost simultaneous with the vibrational cooling [22].
Energy transfer and harvesting in [Ru<inf>1-x</inf>Os<inf>x</inf>(bpy)<inf>3</inf>](PF<inf>6</inf>)<inf>2</inf> and {λ-[Ru(bpy)<inf>3</inf>]δ-[Os(bpy)<inf>3</inf>]} (PF<inf>6</inf>)<inf>4</inf>
2002, Coordination Chemistry ReviewsCitation Excerpt :At low temperature, the emissions stem from substates of a 3MLCT term, while at r.t. also a thermally activated 1MLCT emission has been identified for rac-[Ru(bpy)3](PF6)2 [34,35]. The 3MLCT term splits according to the specific site symmetry of [Ru(bpy)3]2+ and according to spin–orbit coupling into several triplet substates (e.g. see [36–45]). In this outline, we do not discuss group-theoretical assignments, since a generally accepted classification has not yet emerged. (
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