Pulsed-glow discharge/matrix isolation method for the production and trapping of organic ions: application to para-dimethoxybenzene
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Cited by (9)
Measurement and analysis of the infrared absorption spectrum of the radical cation of [3<inf>4</inf>](1, 2, 4,5)cyclophane: Observation of electron-molecular vibration interaction between two benzene moieties
2013, Chemical PhysicsCitation Excerpt :In addition, infrared spectral analysis of ionic species is one of the most promising methods for analyzing the change in electronic structure induced by molecular vibrations, namely the electron–molecular vibration interaction characteristic of the ionic species [5–7]. Efforts have been made to measure reliable and high-quality infrared absorption spectra of organic radical ions and divalent ions produced by various methods such as chemical reactions [5–12], electrochemical techniques [13], electron bombardments [14–20], vacuum ultraviolet photolyses [21–24], pulsed-glow discharge [25,26], X-ray irradiation [27], and low-temperature codeposits with alkali metals [28,29], etc. However, it is not easy to observe the infrared spectra of radical ions and divalent ions, because they are generally unstable at room temperature and in the air.
Infrared measurements of organic radical anions in solution using mid-infrared optical fibers and spectral analyses based on density functional theory calculations
2005, Journal of Molecular StructureCitation Excerpt :Since vibrational spectra are sensitive to changes in molecular structures, vibrational spectroscopy is considered to be useful for studying structural characteristics of ionic species and electron transport in these systems [1–3]. Efforts have been made to measure reliable and high-quality vibrational spectra of organic radical ions produced by various methods including chemical reactions [4–8], electrochemical techniques [9], electron bombardments [10–16], vacuum ultraviolet photolyses [17–20], pulsed-glow discharge [21,22], X-ray irradiation [23], and low temperature codeposits with alkali metals [24,25], etc. However, it is not easy to observe the spectra of radical ions, because they are generally unstable at room temperature and in the air.
A novel source of transient species for matrix isolation studies
1995, Chemical Physics LettersVisible and infrared spectra of matrix-isolated perylene cations
1993, Chemical Physics Letters