On the relative stability of side-on and end-on coordination of dinitrogen to nickel (O): ”ab initio“ calculations on the model compounds [NiN2] and [Ni(PH3)2N2]
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Cited by (14)
Octa-coordination in complexes of lanthanides with N<inf>2</inf> confirmed by matrix-isolation IR spectroscopy and DFT calculations
2023, Journal of Molecular StructureCitation Excerpt :Matrix isolation techniques coupled with diverse spectroscopies provided essential chemical information on metal dinitrogen complexes like FeN2 [9], Ni(NN)x (x = 1-4) [10–15], Pd(NN)x (x = 1-3) [11], or Pt(NN)x (x = 1-3) [12]. The experimental data were supported by theoretical studies on FeN2 [16], Ni(NN)x (x = 1-4) [13,15,17–19], or WNx (x = 1-9) [20]. In recent years the biological nitrogen fixation via the binding of N2 to a metal center in the enzyme nitrogenase received intense attention [7].
Nickel
2004, Comprehensive Coordination Chemistry IIInfrared matrix isolation and DFT study of NiN<inf>2</inf>
1998, Chemical PhysicsOn the nature of the cobalt-nitrogen bond in the CoN<sup>+</sup><inf>2</inf> complex. A theoretical study
1996, Chemical Physics Letters7. Nickel 1991
1995, Coordination Chemistry ReviewsStructure and bonding of lanthanide dinitrogen complexes, Ln(N<inf>2</inf>)<inf>1-8</inf>
2020, International Journal of Quantum Chemistry
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