Use of the Mössbauer isomer shift and the X-ray emission Kα shift to estimate the effective electronic population of iron in complexes
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Chemical effects correlated to nitrogen content of iron nitride films observed in the Fe L-shell X-rays induced by 5-keV electrons
2014, Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and AtomsCitation Excerpt :The L-shell X-rays are affected as well, but have been less analyzed [16–19], as well as the satellite lines [20,21], and the absorption edges [22]. Many efforts have been made to distinguish the oxidation state of iron in minerals using the chemical effect [23], or the X-ray absorption near edge structure (XANES) [24], but only a few studies were related to other ligands of the iron atom than oxygen [3,4,9,13,15]. The electronic shells of free iron atoms are filled until [Ar] 3d5+1− 4s1+1− [25], while ideally Fe3+ corresponds to [Ar] 3d5+ and Fe2+ to [Ar] 3d5+1−.
First principles calculation of Mössbauer isomer shift
2009, Coordination Chemistry ReviewsElectronic structure and spectra of [Fe(CN)<inf>6</inf>SO<inf>3</inf>]<sup>4-</sup>
1992, Spectrochimica Acta Part A: Molecular SpectroscopyOn the correlation between the Mössbauer isomer shift and core electron binding energies of iron
1978, Journal of Electron Spectroscopy and Related PhenomenaMössbauer isomer shifts and the multiple-scattering method
1975, Journal of Physics and Chemistry of SolidsX-ray photoelectron and mössbauer spectroscopy on a variety of iron compounds
1974, Chemical Physics Letters
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