Elsevier

Thermochimica Acta

Volume 83, Issue 1, 15 January 1985, Pages 167-172
Thermochimica Acta

TG and DTA investigations on hexaiodometallates

https://doi.org/10.1016/0040-6031(85)85808-1Get rights and content

Abstract

K2ThI6, Rb2ThI6, Cs2ThI6 and Cs2TiI6 could be prepared from the reactions of alkali metal iodides with ThI4 and TiI4. By precipitation with an excess of alkali metal iodide, Rb2OsI6, Cs2OsI6, K2PtI6 and Rb2PtI6 were obtained from acid solutions of the hexaiodometallate(IV) anions, Rb2OsBr6 was synthesized in a similar way from the corresponding bromine compounds.

The formation of the 4th group hexaiodometallates was investigated by DTA. The thermal stability of the complex salts was determined.

References (8)

  • H.D.B. Jenkins et al.

    Adv. Inorg. Chem. Radiochem.

    (1979)
  • K. Rössler et al.

    Chem. Phys. Lett.

    (1977)
  • D. Sinram et al.

    Inorg. Chim. Acta

    (1982)
  • G. Thiele et al.

    Z. Naturforsch.

    (1983)
There are more references available in the full text version of this article.

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