The Mechanism of the base catalysed carbonato ring opening of cis-[Co(cyclen)CO3]+
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Cited by (3)
CARBONATO COMPLEXES: MODELS FOR CARBONIC ANHYDRASE
2004, Advances in Inorganic ChemistryCitation Excerpt :The spontaneous reactions and the model catalyzed reactions proceed slowly, possibly, due to lack of these environments. In higher vertebrates this enzyme is quite abundant in the brain mainly as the cytosolic isoenzymes CA II, CA IV, and the membrane-bound isoform CA XIV (104,175–179). The inhibition of the brain CA's causes a selective increase of the cerebral blood flow with concomitant rise of carbon dioxide partial pressure (104,175–179).
Kinetics and Mechanism of Ring Opening in the Hydrolysis of Cobalt(III) Carbonato Chelates
1994, Inorganic Chemistry
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