Elsevier

Inorganica Chimica Acta

Volume 96, Issue 1, 3 January 1985, Pages 87-90
Inorganica Chimica Acta

Synthesis and characterization of a new family of binuclear chelate ligands and their copper(II) complexes

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Abstract

A new family of binuclear copper(II) complexes with a flexible bridging group has been prepared by the electrophilic substitution reaction of N-salicylaldehyde-N-acetylacetoneethylenediiminocopper(II) with m-xylene disocyanate or hexamethylene diisocyanate. The de-metallation reaction of the copper(II) complexes with hydrogen sulfide gave the corresponding binuclear chelate ligands.

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