Ruthenium(II) complexes of a 2,2′-biphosphinine
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Cited by (26)
The nicotinamide ruthenium(II) complex induces the production of reactive oxygen species (ROS), cell cycle arrest, and apoptosis in melanoma cells
2023, PolyhedronCitation Excerpt :Time-dependent 31P{1H} NMR experiments at 0, 24, and 48 hours were carried out to evaluate the stability of C1-C3 in DMSO (Figures S42-S44, supporting material). The 31P{1H} NMR spectra of all complexes showed that when the compounds were diluted in DMSO, [RuCl(NIC)(dppb)(X-bipy)]PF6, [RuCl(Py)(dppb)(X-bipy)]PF6, and [RuCl(DMSO)(dppb)(X-bipy)]PF6 were obtained, in agreement with findings reported in the literature [33,54]. A representative 31P{1H} NMR spectra of C3 and respective derivatives in DMSO are shown in Figure 2.
<sup>15</sup>N and <sup>31</sup>P NMR coordination shifts in transition metal complexes with nitrogen- and phosphorus-containing heterocycles
2013, Annual Reports on NMR SpectroscopyCitation Excerpt :− 10 ppm to ca. 60 ppm, Os(II) ca. − 45 ppm, Fe(− 2) ca. 20 ppm, Ru(− 2) ca. 10 ppm (Tables 2.26 and 2.27).273–277,279 In the majority of Ru(II) complexes, the 31P deshielding occurs.273–277
Recent developments in the chemistry of donor-functionalized phosphinines
2010, Comptes Rendus ChimieRuthenium and Osmium: Low Oxidation States
2003, Comprehensive Coordination Chemistry IITransition metals in phosphinine chemistry
1998, Coordination Chemistry ReviewsSynthesis and X-ray crystal structures of dimeric nickel(0) and tetrameric copper(I) iodide complexes of 2-diphenylphosphino-3-methylphosphinine
1997, Journal of Organometallic Chemistry
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