trans-Bis(tetracarbonylcobaltato)bis(pyridine)platinum(II) and trans-bis(pentacarbonylmanganato)bis(pyridine)- platinum(II)

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Abstract

The preparation and properties of trans-PtPy2[Co(CO)4]2 and trans- PtPy2[Mn(CO)5]2 are described. The metal carbonyl anion Co(CO)4 is studied as a leaving group by measuring the rate of the cleavage reaction PtPy2[Co(CO)4]2+2 Y ⇌ [PtPy2Y2]2+ + 2 Co(CO)4 Y = (C6H5)3P, (n-C4H9)3P in tetrahydrofuran. The products of these reactions are also described.

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Permanent address: Institute de Chimie, Boite Postale 296/R8, Universiteé de Strasbourg, 67-Strasbourg, France. NATO Fellow, 1966–1967.

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