Bipolaronic state of V4+ ion pair in the quasi-one-dimensional conductor MxV2O5 systems

doi:10.1016/0304-8853(83)90839-9

Journal of Magnetism and Magnetic Materials

Volumes 31–34, Part 3, February 1983, Pages 1153-1154

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Abstract

In quasi-one-dimensional conductor M_xV₂O₅ where the mixed valent V⁴⁺ and V⁵⁺ ions from zig-zag chains, the CDW state were observed below about 200 K in monoclinic phases by X-ray diffraction. The ⁵¹V Knight shift results show the spin-singlet ground state of V⁴⁺ ion pair (‘bipolaron’) is realized.

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Cited by (1)

Properties of Bipolaron System
1983, Journal of the Physical Society of Japan

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Bipolaronic state of V4+ ion pair in the quasi-one-dimensional conductor MxV2O5 systems

Abstract

Solid State Commun.

Solid State Commun.

J. Solid State Chem.

Phys. Rev.

Phys. Rev. Lett.

Bull. Chem. Soc. Japan

Bipolaronic state of V⁴⁺ ion pair in the quasi-one-dimensional conductor M_xV₂O₅ systems