Valency and covalency in high-Tc-superconductors from x-ray absorption

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Abstract

The local electronic structure of the high-Tc superconductors YBa2Cu3O7−δ and Nd2−xCexCuO4−δ is probed by soft x-ray absorption spectroscopy at the Cusingle bondLII,III, Osingle bondK, Cesingle bondMIV,V, and Ndsingle bondMIV,V thresholds. The near-edge structures provide information on the partial unoccupied density of states above EF as well as on valency and covalency of the constituent elements.

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On leave from AGH, Krakow, Poland.

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