Biochemical and Biophysical Research Communications
A novel methoxyindole glucosinolate
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Glucosinolate structural diversity, identification, chemical synthesis and metabolism in plants
2020, PhytochemistryCitation Excerpt :A further discovered N-methoxy derivative was named neoglucobrassicin (Gmelin and Virtanen, 1962) (Fig. 5). However, when two additional structures (28, 48) were discovered (Truscott et al., 1982a; 1982b), the authors wisely abstained from continuing this naming tradition. The name progoitrin is an early name that follows its own logic, being the precursor of goitrin (Greer, 1956) (Fig. 9).
Glucosinolate structures in evolution
2012, PhytochemistryCitation Excerpt :Fenwick et al. (1983) listed 21 new structures reported in the preceding decade and concluded the total number of known GSLs to be “over 90”, but noted that several should be regarded as tentative. Notable discoveries in the 1980’ies included 4-hydroxy (28) and 4-methoxy (48) derivatives of indol-3-ylmethylGSL (Truscott et al., 1982a,b), discovered during the remarkable analytical progress (Sang et al., 1984; Wathelet, 1987) that was part of the successful attempts to convert classical oil seed rape (Brassica napus and Brassica campestris) into the “double low” quality (low in GSLs and erucic acid), also known as “canola”. Trace levels of socalled ‘selenoGSLs’, defined as GSL-like metabolites with the thioglucosyl moiety replaced by a selenoglucosyl moiety, were reported from a selenium-tolerant crucifer but only when exposed to unusually high levels (100 ppm Se) of sodium selenite added to nutrient solutions (Bertelsen et al., 1988).
Study of natural ascorbigen and related compounds by HPLC
1992, Food Chemistry4-Methoxybrassinin, a sulphur-containing phytoalexin from Brassica oleracea
1990, PhytochemistryIndole glucosinolates of Capparis spinosa
1989, Phytochemistry