The far-infrared spectra of a series of hydrogen bonded complexes

doi:10.1016/0584-8539(72)80213-7

Spectrochimica Acta Part A: Molecular Spectroscopy

Volume 28, Issue 12, December 1972, Pages 2331-2342

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Abstract

The i.r. spectra of each of the 24 uni-unimolecular hydrogen bonded complexes formed by phenol, 4-Me, 4-F, 4-Cl, 4-Br and 4-I phenol with pyridine, 4-Me, 4-Et and 4-Ph pyridine have been measured over the range 450-80 cm⁻¹. An assignment of all the observed bands is made, and in all the complexes an intermolecular band distinguished, which is ascribed to stretching of the hydrogen bond ν_σ. The frequency is compared with the shift of the OH stretching frequency Δν_s, which has also been measured for each complex.

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¹: Now at the University of Mocambique, Lourenço Marques, Portuguese East Africa.

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The far-infrared spectra of a series of hydrogen bonded complexes

Abstract

Spectrochim. Acta

J. Am. Chem. Soc.

Spectrochim. Acta

J. Chim. Phys.

Spectrochim. Acta

J. Chim. Phys.

Bull. Soc. Chim. Belg.

J. Phys. Chem.

Acta. Chim. Scand.

J. Phys. Chem.

Spectrochim. Acta