Solid state vibrational spectroscopy of disordered crystals. A study of dimethylsulphoxide at 213 K

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Abstract

The vibrational spectrum of crystalline dimethylsulphoxide at 213 K has been studied by i.r. and Raman spectroscopy. Such an experiment is proposed as an example to show how much the dipole-dipole interaction forces can affect the molecular disorder often observed in molecular crystals of compounds containing sulphur atoms.

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