Abstract
THAT the cupric salts of alkanoic acids occur in the solid state in the form of dimeric molecules is shown by van Niekerk and Schoening's X-ray analysis of cupric acetate hydrate (I, R = CH3, L = H2O)1 and by Martin and Waterman's magnetic studies of the acetate and some higher homologues in hydrated and anhydrous forms2. Tsuchida and Yamada have shown that a further characteristic of this structure is the occurrence of an absorption band about 375 mµ, polarized in the copper–copper axis, in addition to the usual ‘copper band’ about 700 mµ3,4.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
van Niekerk, J. N., and Schoening, F. R. L., Nature, 171, 36 (1953).
Martin, R. L., and Waterman, H., J. Chem. Soc., 3545 (1957).
Tsuchida, R., and Yamada, S., Nature, 176, 1171 (1955).
Tsuchida, R., Yamada, S., and Nakamura, H., Nature, 181, 479 (1958).
Martin, R. L., and Waterman, H., J. Chem. Soc., 1394 (1958).
Graddon, D. P., J. Inorg. Nuc. Chem., 11, 337 (1959).
Martin, R. L., and Waterman, H., J. Chem. Soc., 1359, 2960 (1959).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
GRADDON, D. Nature of Cupric Alkanoate Solutions. Nature 186, 715–716 (1960). https://doi.org/10.1038/186715b0
Issue Date:
DOI: https://doi.org/10.1038/186715b0
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.